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Statement I : | Both \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) and \(\left[\text{CoF}_6\right]^{3-}\) Complexes are octahedral but differ in their magnetic behaviour. |
Statement II : | \(\left[\text{Co}\left(\text{NH}_3\right)_6\right]^{3+}\) is diamagnetic whereas \(\left[\text{CoF}_6\right]^{3-}\) is paramagnetic. |
Statement I: | The boiling point of hydrides of Group 16 elements follow the order \(\text{H}_2 \text{O}>\text{H}_2 \text{Te}>\text{H}_2 \text{Se}>\text{H}_2 \text{S} .\) |
Statement II: | On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point. |
1. | Li < B < Be < C < N | 2. | Li < Be < C < B < N |
3. | Li < Be < N < B < C | 4. | Li < Be < B < C < N |
1. | Probability of collision. |
2. | Orientation of reactant molecules during collision. |
3. | Rate constant at two different temperatures. |
4. | Rate constant at standard temperature. |
1. | Si < C < O < N < F | 2. | O < F < N < C < Si |
3. | F < O < N < C < Si | 4. | Si < C < N < O < F |
List I Quantum Number |
List II Information provided |
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A. | ml | I. | Shape of the orbital |
B. | ms | II. | Size of the orbital |
C. | l | III. | Orientation of the orbital |
D. | n | IV. | Orientation of spin of the electron |
1. | A-III, B-IV, C-I, D-II | 2. | A-III, B-IV, C-II, D-I |
3. | A-II, B-I, C-IV, D-III | 4. | A-I, B-III, C-II, D-IV |
List I (Compound) |
List II (Shape/geometry) |
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A. | NH3 | I. | Trigonal Pyramidal |
B. | BrF5 | II. | Square planar |
C. | XeF4 | III. | Octahedral |
D. | SF6 | IV. | Square Pyramidal |