Q. No.The nitration of aniline in a strong acidic medium results in the formation of m-nitroaniline because:
1.
In spite of substituents, the nitro group always goes to only the m-position.
2.
In electrophilic substitution reactions, the amino group is meta-directive.
3.
In the absence of substituents, the nitro group always goes to only m-position.
4.
In an acidic (strong) medium, aniline is present as an anilinium ion.
A nitrogen-containing aromatic compound A reacts with Sn/HCl, followed by HNO2 to give an unstable compound B. On treatment with phenol, B forms a beautiful coloured compound C with the molecular formula C12H10N2O. The structure of compound A is:
| 1. |  |
2. |  |
| 3. |  |
4. |  |
The correct statement regarding the basicity of arylamines is:
| 1. | Arylamines are generally more basic than alkylamines because the lone-pair electrons of nitrogen are not delocalized by interaction with the aromatic ring π-electron system. |
| 2. | Arylamines are generally more basic than alkylamines because of the aryl group +I effect. |
| 3. | Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hybridized. |
| 4. | Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring π-electron system. |
The number of structural isomers possible from the molecular formula C3H9N is?
1. 4
2. 5
3. 2
4. 3
Mark the reaction that does not yield aniline from the given options:
| 1. | Hydrolysis of phenyl isocyanide with an acidic solution |
| 2. | Degradation of benzamide with bromine in alkaline solution |
| 3. | Reduction of nitrobenzene with H2/Pd in ethanol |
| 4. | Treatment of potassium salt of phthalimide with chlorobenzene followed by hydrolysis in an aqueous NaOH solution |
What is the name of the following reaction?
1. Friedel-Crafts reaction
2. Perkins reaction
3. Acetylation reaction
4. Schotten-Baumann reaction
The most stable diazonium salt among the following is:
1. \(CH_{3}N_{2}^{+}X^{-}\)
2. \(C_{6}H_{5}N_{2}^{+}X^{-}\)
3. \(CH_{3}CH_{2}N_{2}^{+}X^{-}\)
4. \(C_{6}H_{5}CH_{2}N_{2}^{+}X^{-}\)
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