Q. No.A compound "A", when reacted with PCl5 and then with ammonia, gives "B". "B" on treatment with bromine and caustic potash produces "C". "C" on treatment with NaNO2 and HCl at C and then boiling produces ortho-cresol. Compound "A" is:
1. o-Toluic acid
2. o-Chlorotoluene
3. o-Bromotoluene
4. m-Toluic acid
The reaction of propanamide with ethanolic sodium hydroxide and bromine will give:
| 1. | Ethylamine | 2. | Methylamine |
| 3. | Propylamine | 4. | Aniline |
In the conversion of nitromethane to methylamine, the reagent that is used is:
| 1. | \(\mathrm{SOCl}_2 \) | 2. | \(\mathrm{NaNH}_2 \) |
| 3. | \(\mathrm{PCl}_5 \) | 4. | \(\mathrm{Sn} / \mathrm{HCl}\) |
Select the correct option based on statements below:
| Assertion (A): | Only a small amount of HCI is required in the reduction of nitro compounds with iron scrap and HCI in the presence of steam. |
| Reason (R): | FeCl2 formed gets hydrolyzed to release HCI during the reaction. |
| 1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false. |
Select the correct option based on statements below:
| Assertion (A): | N-ethylbenzene sulphonamide is soluble in alkali. |
| Reason (R): | The hydrogen attached to nitrogen in sulphonamide is strongly acidic. |
| 1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | (A) is false but (R) is true. |
Match the compounds given in Column I with the items given in Column II.
| Column I | Column II |
| A. Benzene sulphonyl chloride | 1. Zwitter ion |
| B. Sulphanilic acid | 2. Hinsberg reagent |
| C. Alkyl diazonium salts | 3. Dyes |
| D. Aryl diazonium salts | 4. Conversion to alcohols |
Codes
| A | B | C | D | |
| 1. | 2 | 1 | 4 | 3 |
| 2. | 3 | 1 | 4 | 2 |
| 3. | 1 | 4 | 3 | 2 |
| 4. | 4 | 3 | 2 | 1 |
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II |
| A. Ammonolysis | 1. Amine with a lesser number of carbon atoms |
| B. Gabriel phthalimide synthesis | 2. Detection test for primary amines. |
| C. Hofmann bromamide reaction | 3. Reaction of phthalimide with KOH and R—X |
| D. Carbylamine reaction | 4. Reaction of alkyl halides with NH3 |
Codes
| A | B | C | D | |
| 1. | 2 | 3 | 4 | 1 |
| 2. | 3 | 1 | 4 | 2 |
| 3. | 1 | 4 | 3 | 2 |
| 4. | 4 | 3 | 1 | 2 |
A compound among the following that does not undergo an azo coupling reaction with benzene diazonium chloride is:
1. Aniline
2. Phenol
3. Anisole
4. Nitrobenzene
In nitration of benzene using a mixture of conc. H2SO4 and conc. HNO3, the species that initiates the reaction is :
1. NO2
2. NO+
3. NO2+
4. NO2-
The most effective reagent among the following to convert 2-phenylpropanamide into 2-phenylpropanamine is:
| 1. | Excess H2 |
| 2. | Br2 in aqueous NaOH |
| 3. | Iodine in the presence of phosphorus |
| 4. | LiAlH4 in ether |
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