In this reaction,

\(CH_{3}CHO \ + \ HCN \ \xrightarrow[]{} \ CH_{3}CH(OH)CN \ \xrightarrow[]{\textbf{H.OH}} \\ CH_{3}CH(OH)COOH\)

an asymmetric compound is generated. The acid obtained would be:        

1. 50% D + 50% L-isomer

2. 20% D + 80% L-isomer

3. D-isomer

4. L-isomer

Subtopic:  Isomers & Reaction Mechanism |
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Which of the following is the most reactive towards nucleophilic addition reaction?
1.    2.
3.   4.  
Subtopic:  Isomers & Reaction Mechanism |
 83%
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AIPMT - 2014
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The Grignard reagent is added to methanal and hydrolyzed to produce:

1. Primary alcohol 2. Tertiary alcohol
3. Methane  4. Methanoic acid
Subtopic:  Isomers & Reaction Mechanism |
 83%
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The major product formed when cyclohexanecarbaldehyde reacts with PhMgBr and H3O+ is:

1.  2.
3. 4.  None of these
Subtopic:  Aldehydes & Ketones: Preparation & Properties | Isomers & Reaction Mechanism |
 84%
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HCN not produce a chiral compound with:

1.  2.
3. 4.
 

Subtopic:  Isomers & Reaction Mechanism |
 83%
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An alkene “A” on reaction with O3 and Zn - H2O gives propanone and ethanal in an equimolar ratio. The addition of HCl to alkene “A” gives “B” as the major product. The structure of product “B” is:

1.  2.
3. 4.
 

Subtopic:  Isomers & Reaction Mechanism |
 82%
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Which of the following compounds produces a pink colour when combined with Schiff's reagent?

1. CH3CHO 

2. CH3CH2COOH

3. C3H5COOH 

4. C6H5COC6H5

Subtopic:  Isomers & Reaction Mechanism |
 77%
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What is present in acetone's enolic form?

1. 9 σ-bonds, 1π-bond and 2 lone pairs

2. 8 σ-bonds, 2π-bonds and 2 lone pairs

3. 10 σ-bonds, 1π-bond and 1 lone pair

4. 9 σ-bonds, 2π-bonds and 1 lone pair

Subtopic:  Isomers & Reaction Mechanism |
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A compound A, when reacted with PCl5 and then with ammonia, gave B. B, when treated with bromine and caustic potash, produced C. C on treatment with NaNO2 and HCl at 0°C and on boiling produced ortho-cresol. Compound A is:

1. o-Toluic acid 2. o-Chlorotoluene
3. o-Bromotoluene 4. m-Toluic acid
Subtopic:  Isomers & Reaction Mechanism |
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Select the correct option based on statements below:

Assertion (A): Compounds containing —CHO group are easily oxidised to corresponding carboxylic acids.
Reason (R): Carboxylic acids can be reduced to alcohol by treatment with LiAlH4.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.
Subtopic:  Isomers & Reaction Mechanism |
 80%
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