The correct splitting diagram of d orbitals in an octahedral crystal field is:

1. 2.
3. 4.  
None of the above

Subtopic:  VBT, CFT & their Limitations |
 88%
Level 1: 80%+
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Optical isomerism is exhibited by among the following is/are:

1. [Cr(Ox)3]3- 2. [PtCl2(en)2]2+
3. [Cr(NH3)2Cl2en]+ 4. All of the above
Subtopic:  Isomerism in Coordination Compounds |
 79%
Level 2: 60%+
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The correct representation of Potassium tris(oxalato) chromate(III) is:

1. K2Cr(C2O4)3
2. K3Cr(C2O4)3
3. K3Cr(C2O4)2
4. K2Cr(C2O4)4

Subtopic:  Introduction, Classification and Nomenclature |
 90%
Level 1: 80%+
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The correct representation of tetrahydroxidozincate (II) is:
1. \([Zn(OH)_4]^{2-}\)
2. \([Zn(OH)_4]^{-}\)
3. \([Zn(OH)_4]^{3-}\)
4. \([Zn(OH)_4]\)

Subtopic:  Introduction, Classification and Nomenclature |
 92%
Level 1: 80%+
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A solution of [Ni(H2O)6]2+ is green, but a solution of [Ni(CN)4]2– is colorless because:

1. There are paired electrons in [Ni(H2O)6]2+ while all electrons are unpaired in [Ni(CN)4]2–
2. There are unpaired electrons in [Ni(H2O)6]2+ while all electrons are paired in [Ni(CN)4]2–
3. There are unpaired electrons in [Ni(H2O)6]2+ and [Ni(CN)4]2–
4. None of the above.

Subtopic:  Introduction, Classification and Nomenclature |
 87%
Level 1: 80%+
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[Cr(NH3)6]3+ is paramagnetic ,while Ni(CN)42- is diamagnetic because:

1. Electrons in the 3d orbitals remain unpaired in Ni(CN)42-
2. Electrons in the 3d orbitals remain unpaired in [Cr(NH3)6]3+
3. Electrons in the 3p orbitals remain unpaired in [Cr(NH3)6]3+
4. Electrons in the 3p orbitals remain unpaired in Ni(CN)42-

Subtopic:  VBT, CFT & their Limitations |
 90%
Level 1: 80%+
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The crystal field splitting energy is:

1. The heat of formation between the two levels (e and t2) in tetrahedral splitting
2. The total pairing energy of the two levels (e and t2) in tetrahedral splitting.
3. The sum of the energy levels in an octahedral crystal field splitting.
4. The combined energy of the two levels (eg and t2g) in octahedral splitting.

Subtopic:  VBT, CFT & their Limitations |
 61%
Level 2: 60%+
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How many optical isomers of [Pt(NH3)(Br)(Cl)(py)] can exist?

1. 3

2. 2

3. 1

4. 0

Subtopic:  Introduction, Classification and Nomenclature |
Level 3: 35%-60%
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A metal ion present in vitamin B12 is:

1. Fe(II) 2. Co(III)
3. Zn(II) 4. Ca(II)
Subtopic:  Organometallic Complexes & their Uses |
 79%
Level 2: 60%+
AIPMT - 2003
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The hypothetical complex
chlorodiaquatriamminecobalt(III) chloride can be
represented as:

1. CoClNH33H2O2Cl2

2. CoNH33H2OCl3

3. CoNH23H2O2Cl

4. CoNH33H2O3Cl3

Subtopic:  Introduction, Classification and Nomenclature |
 80%
Level 1: 80%+
AIPMT - 2002
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