The correct splitting diagram of d orbitals in an octahedral crystal field is:
| 1. | 2. | ![]() |
|
| 3. | 4. | None of the above |
Optical isomerism is exhibited by among the following is/are:
| 1. | [Cr(Ox)3]3- | 2. | [PtCl2(en)2]2+ |
| 3. | [Cr(NH3)2Cl2en]+ | 4. | All of the above |
The correct representation of tetrahydroxidozincate (II) is:
1. \([Zn(OH)_4]^{2-}\)
2. \([Zn(OH)_4]^{-}\)
3. \([Zn(OH)_4]^{3-}\)
4. \([Zn(OH)_4]\)
A solution of [Ni(H2O)6]2+ is green, but a solution of [Ni(CN)4]2– is colorless because:
| 1. | There are paired electrons in [Ni(H2O)6]2+ while all electrons are unpaired in [Ni(CN)4]2– |
| 2. | There are unpaired electrons in [Ni(H2O)6]2+ while all electrons are paired in [Ni(CN)4]2– |
| 3. | There are unpaired electrons in [Ni(H2O)6]2+ and [Ni(CN)4]2– |
| 4. | None of the above. |
[Cr(NH3)6]3+ is paramagnetic ,while is diamagnetic because:
| 1. | Electrons in the 3d orbitals remain unpaired in |
| 2. | Electrons in the 3d orbitals remain unpaired in [Cr(NH3)6]3+ |
| 3. | Electrons in the 3p orbitals remain unpaired in [Cr(NH3)6]3+ |
| 4. | Electrons in the 3p orbitals remain unpaired in |
The crystal field splitting energy is:
| 1. | The heat of formation between the two levels (e and t2) in tetrahedral splitting |
| 2. | The total pairing energy of the two levels (e and t2) in tetrahedral splitting. |
| 3. | The sum of the energy levels in an octahedral crystal field splitting. |
| 4. | The combined energy of the two levels (eg and t2g) in octahedral splitting. |
How many optical isomers of [Pt(NH3)(Br)(Cl)(py)] can exist?
1. 3
2. 2
3. 1
4. 0
A metal ion present in vitamin B12 is:
| 1. | Fe(II) | 2. | Co(III) |
| 3. | Zn(II) | 4. | Ca(II) |
The hypothetical complex
chlorodiaquatriamminecobalt(III) chloride can be
represented as:
1.
2.
3.
4.