Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?

1. Xe4 f8 6d2

2. Xe4 f9 5s1

3. Xe4 f7 5d16s2

4. Xe4 f6 5d26s2

Subtopic:  f-Block Elements- Properties & Uses |
 90%
From NCERT
NEET - 2015
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Assuming complete ionization, same moles of which of the following compounds will require the least amount of acidified KMnO4 for complex oxidation?

1. FeSO4

2. FeSO3

3. FeC2O4

4. FeNO22

Subtopic:  d-Block Elements- Properties & Uses |
 52%
From NCERT
NEET - 2015
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A pair among the following have nearly the same atomic radii:

(Numbers in the parenthesis are atomic numbers).

1. Ti (22) and Zr (40)
2. Zr (40) and Nb (41)
3. Zr (40) and Hf (72)
4. Zr (40) and Ta (73)

Subtopic:  f-Block Elements- Properties & Uses | Lanthanoid & Actinoids Contraction |
 90%
From NCERT
NEET - 2015
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Which of the following processes does not involve the oxidation of iron?

1. Rusting of iron sheets
2. Decolourisation of blue CuSO4 solution by iron
3. Formation of Fe(CO)from Fe
4. Liberation of H2 from steam by iron at high temperature

Subtopic:  d-Block Elements- Properties & Uses |
 69%
From NCERT
NEET - 2015
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The pair of compounds that can exist together is:

1. FeCl3, SnCl2

2. HgCl, SnCl2

3. FeCl2, SnCl2

4. FeCl3, Kl

Subtopic:  d-Block Elements- Properties & Uses |
 52%
From NCERT
AIPMT - 2014
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In acidic medium, H2O2 changes Cr2O7–2 to CrO5 which has two (–O – O–) bonds.
The oxidation state of Cr in CrO5 is:

1. +5

2. +3

3. +6

4. -10

Subtopic:  Chemistry of Mn and Cr Compounds |
 74%
From NCERT
AIPMT - 2014
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The reason for the lanthanoid contraction is:

1. negligible screening effect of 'f' orbitals.

2. increasing nuclear charge.

3. decreasing nuclear charge.

4. decreasing screening effect.

Subtopic:  Lanthanoid & Actinoids Contraction |
 76%
From NCERT
AIPMT - 2014
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Identify the correct order of solubility in aqueous medium:
1. ZnS > Na2S > CuS
2. Na2S > CuS > ZnS
3. Na2S > ZnS > Cus
4. Cus > ZnS > Na2S

Subtopic:  d-Block Elements- Properties & Uses |
AIPMT - 2013
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Diamagnetic lanthanoid ion among the following is:
(At nos. Ce = 58, Sm = 62, Eu = 63, Yb = 70)
1. Sm2+
2. Eu2+
3. Yb2+
4. Ce2+
Subtopic:  f-Block Elements- Properties & Uses |
 61%
From NCERT
AIPMT - 2013
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Considering the following reaction,
3 MnO 42– + 2 H 2 O ⇌ 2 MnO 4 + MnO 2 + 4 OH
The reagent that facilitates the removal of OH ions to ensure the completion of the conversion of K2MnO4 to KMnO4 is:

1. KOH
2. CO2
3. SO2
4. HCl
Subtopic:  Chemistry of Mn and Cr Compounds |
From NCERT
AIPMT - 2013
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