1. | d5 to d2 configuration | 2. | d4 to d5 configuration |
3. | d3 to d5 configuration | 4. | d5 to d4 configuration |
Which of the following ions have the same 'spin-only' magnetic moment?
A. | Ti+3 | B. | Cr2+ |
C. | Mn2+ | D. | Fe2+ |
E. | Sc3+ |
Choose the most appropriate answer from the options given below:
1. | A and E only | 2. | B and C only |
3. | A and D only | 4. | B and D only |
List-I (Element) |
List-II (Most Common oxidation state/s) |
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A. | \(\mathrm{Fe}\) | I. | +2, +7 |
B. | V | II. | +3, +2 |
C. | \(\mathrm{Mn}\) | III. | +4 |
D. | \(\mathrm{Ti}\) | IV. | +5 |
1. | A-II, B-IV, C-I, D-III | 2. | A-IV, B-II, C-I, D-III |
3. | A-II, B-I, C-IV, D-III | 4. | A-I, B-IV, C-II, D-III |
1. | C and D only | 2. | A and D only |
3. | A and B only | 4. | B and C only |
A. | All the transition metals except scandium form MO oxides which are ionic. |
B. | The highest oxidation number corresponds to the group number in transition metal oxides is attained in Sc2O3 to Mn2O7. |
C. | Basic character increases from V2O3 to V2O4 to V2O5. |
D. | V2O4 dissolves in acids to give VO43-. |
E. | CrO is basic, but Cr2O3 is amphoteric. |
1. | B and C only | 2. | A and E only |
3. | B and D only | 4. | C and D only |
Assertion (A): | Ionization enthalpy increases along each series of transition elements from left to right. However, small variations occur. |
Reason (R): | There is a corresponding increase in nuclear charge which accompanies the filling of electrons in the inner d-orbitals. |
1. | (A) is correct but (R) is not correct |
2. | (A) is not correct but (R) is correct |
3. | Both (A) and (R) are correct and (R) is the correct explanation of (A) |
4. | Both (A) and (R) are correct but (R) is not the correct explanation of (A) |
1. | +6 to +5 | 2. | +7 to +4 |
3. | +6 to +4 | 4. | +7 to +3 |
Match the statements given in List I with the corresponding element given in List II:
List-I (Characteristics) |
List-II (Elements) |
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(a) | Element that exhibits +3 oxidation state only. | (i) | Mn |
(b) | An element that exhibits more number of oxidation states. | (ii) | Zn |
(c) | Element which is a reducing agent in its +2 oxidation state. | (iii) | Sc |
(d) | An element that is not considered as a transition element. | (iv) | Cr |
(a) | (b) | (c) | (d) | |
1. | (iii) | (iv) | (i) | (ii) |
2. | (iv) | (i) | (ii) | (iii) |
3. | (ii) | (iv) | (iii) | (i) |
4. | (iii) | (i) | (iv) | (ii) |