| Assertion (A): | R3P=O exists but R3N=O does not where R= alkyl group). |
| Reason (R): | Nitrogen doesn't have d orbitals. |
| 1. | (A) is true and (R) is the correct explanation of (A). |
| 2. | (A) is true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false |
Match the formulas of oxides given in Column I with the type of oxide given in Column II and mark the correct option.
| Column I | Column II |
| A. Pb3O4 | 1. Neutral oxide |
| B. N2O | 2. Acidic oxide |
| C. Mn2O7 | 3. Basic oxide |
| D. Bi2O3 | 4. Mixed oxide |
Codes
| A | B | C | D | |
| 1. | 1 | 2 | 3 | 4 |
| 2. | 4 | 1 | 2 | 3 |
| 3. | 3 | 2 | 4 | 1 |
| 4. | 4 | 3 | 1 | 2 |
Which of the following statements are correct?
| a. | Among halogens, the radius ratio between iodine and fluorine is maximum. |
| b. | Leaving F — F bond, all halogens have weaker X — X bond than X — X' bond in interhalogens. |
| c. | Among interhalogen compounds a maximum number of atoms are present in iodine fluoride. |
| d. | Interhalogen compounds are more reactive than halogen compounds. |
1. a, b, and c
2. b, c, and d
3. a, c, and d
4. a, b, and d
Which of the following statements are correct for SO2 gas?
| a. | It acts as a bleaching agent in moist conditions. |
| b. | Its molecule has linear geometry. |
| c. | Its dilute solution is used as a disinfectant. |
| d. | It can be prepared by the reaction of dilute H2SO4 with metal sulphide. |
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)
Which of the following statements are correct?
| a. | All the three N – O bond lengths in HNO3 are equal. |
| b. | All P – Cl bond lengths in PCl5 molecule in the gaseous state are equal. |
| c. | P4 molecule in white phosphorus have angular strain therefore white phosphorus is very reactive. |
| d. | PCl5 is ionic in a solid-state in which cation is tetrahedral and the anion is octahedral. |
Which of the following statements are correct?
| a. | S — S bond is present in H2S2O6 |
| b. | In peroxosulphuric acid (H2SO5) sulphur is in +6 oxidation state |
| c. | Iron powder along with Al2O3 and K2O is used as a catalyst in the preparation of NH3 by Haber's process |
| d. | Change in enthalpy is positive for the preparation of SO3 by catalytic oxidation of SO2 |
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)
Which of the following statements is/are true?
| a. | Only types of interactions between particles of noble gases are due to weak dispersion forces. |
| b. | The ionization enthalpy of molecular oxygen is very close to that of xenon. |
| c. | Hydrolysis of XeF6 is a redox reaction. |
| d. | Xenon fluorides are not reactive. |
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)
Match the compounds given in Column I with the hybridisation and shape given in Column II and mark the correct option.
| Column I | Column II | ||
| A | XeF6 | 1. | sp3d3 distorted octahedral |
| B. | XeO3 | 2. | sp3d2 square planar |
| C. | XeOF4 | 3. | sp3 pyramidal |
| D. | XeF4 | 4. | sp3d2 square pyramidal |
Codes:
| Options: | A | B | C | D |
| 1. | 1 | 3 | 4 | 2 |
| 2. | 1 | 2 | 4 | 3 |
| 3. | 4 | 3 | 1 | 2 |
| 4. | 4 | 1 | 2 | 3 |
Match the items in Columns I and II and mark the correct option.
| Column I | Column II |
| A. H2SO4 | 1. Highest electron affinity |
| B. CCl3NO2 | 2. Chalcogen |
| C. Cl2 | 3. Tear gas |
| D. Sulphur | 4. Storage batteries |
Codes:
| A | B | C | D | |
| 1. | 4 | 3 | 1 | 2 |
| 2. | 3 | 4 | 1 | 2 |
| 3. | 4 | 1 | 2 | 3 |
| 4. | 2 | 1 | 3 | 4 |
Match the species given in Column I with the shape given in Column II and mark the correct option:
| Column I (Species) | Column II (Shape) | ||
| A. | \(\mathrm{SF}_4\) | (I) | Tetrahedral |
| B. | \(\mathrm{BrF}_3\) | (II) | Pyramidal |
| C. | \(\mathrm{BrO}_3^{-}\) | (III) | Sea-saw shaped |
| D. | \(\mathrm{NH}_4^{+}\) | (IV) | Bent T-shaped |
Codes:
| A | B | C | D | |
| 1. | III | II | I | IV |
| 2. | III | IV | II | I |
| 3. | I | II | III | IV |
| 4. | I | IV | III | II |