For a 1st order reaction following graph is obtained between lnk and \({1000 \over T}\). Then activation energy of reaction in kcal is : 
         

1. 37 kcal
2. 40 kcal
3. 42 kcal
4. 34 kcal
Subtopic:  Arrhenius Equation |
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For the reaction, aA+bBcC+dD the plot of log k vs 1T is given below :

Find the temperature(K) at which the rate constant of the reaction is 10–4s–1 ?

(Rounded-off to the nearest integer) 

[Given: The rate constant of the reaction is 105 s1 at 500 K.] 

1. 546 K 2. 536 K
3. 516 K 4. 526 K
Subtopic:  Arrhenius Equation |
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The rate constant of a reaction increases by five times on increase in temperature from 27°C to 52°C. The value of activation energy in kJ mol–1 is-

(Rounded-off to the nearest integer) [R = 8.314 J K–1 mol–1]

1. 50

2. 56

3. 52

4. 60

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The rate constant (k) of a reaction is measured at different temperatures (T), and the data are plotted in the given figure. The activation energy of the reaction in kJ mol–1 is:
(R is gas constant)

1.  2R
2.  R
3.  1/R
4.  2/R

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The rate of a reaction is decreased by 3.555 times when the temperature was changed from 40°C to 30°C. The activation energy (in kJ mol-1) of the reaction is:
(Take R=8.314 J mol-1 K-1 In 3.555=1.268)

1. 100 kJ/mol
2. 120 kJ/mol
3. 95 kJ/mol
4. 108 kJ/mol

Subtopic:  Arrhenius Equation |
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Two reactions, R1 and R2 have identical pre-exponential factors. Activation energy of R1 exceeds that of R2 by 10 kJ mol–1. If k1 and k2 are rate constants for reactions R1 and R2 respectively at 300 K, then ln(k2/k1) is equal to:

(R = 8.314 J mol–1 K–1).

1. 6

2. 4

3. 8

4. 12

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Which of the following statements is correct regarding the equation k = Ae-Ea/RT

1. k is the equilibrium constant 

2. A is adsorption factor 

3. Ea is the energy of activation 

4. R is the Rydberg constant 

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The activation energy of one of the reactions in a biochemical process is \(\mathrm{532611~ J~ mol^{–1} .}\) When the temperature falls from \(\mathrm{310~ K}\) to \(\mathrm{300~ K,}\) the change in rate constant observed is \(\mathrm{k_{300} = x × 10^{–3} k_{310}.}\)
The value of \(\mathrm{x}\) is:
[Given: ln\(\mathrm{10 = 2.3, R = 8.3 ~JK^{–1} mol^{–1}}\) ]
1. 1 2. 5
3. 2 4. 8
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