The relationship between temperature and the variance in reaction rate is:

1.  2.
3. 4.

Subtopic:  Arrhenius Equation |
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Half-life is independent of the concentration of a reactant. After 10 minutes, the volume of N2 gas is 10 L and after complete reaction, it is 50 L. Hence, the rate constant is:

1. 2.30310log 5 min-1

2. 2.30310 log 1.25 min-1

3. 2.30310 log 2 min-1

4. 2.30310 log 4 min-1

Subtopic:  First Order Reaction Kinetics |
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Consider the following graph

Choose the incorrect statement(s)

1.  Reaction is exothermic forward direction i.e., H = -ve

2.  Activation energy for forward reaction is x - y

3.  Using catalyst energy will decrease H value of the reaction

4.  All of these

Subtopic:  Catalyst |
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The half-life for radioactive decay of 14C is 5730 years. A wood sample contains only 80% of the 14C. The age of the wood sample would be-

1. 1898 years

2. 1765 years

3. 1931 years

4. 1860 years

Subtopic:  First Order Reaction Kinetics |
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Sucrose hydrolysis in an acidic solution into glucose and fructose follows the first-order rate law with a half-life of 3.33 h at 25°C. After 9 h, the fraction of sucrose remaining is f. The value of  \(log(\frac{1}{f})\) is A×10-2 . The value of A is:
(Rounded off to the nearest integer) [Assume : ln 10 = 2.303, ln 2 = 0.693]
1. 78
2. 81
3. 85
4. 75

Subtopic:  First Order Reaction Kinetics |
 72%
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Consider the reaction, 2A + B → Products.
When concentration of B alone was doubled, the half-life did not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is:

1. L mol–1 s–1

2. no unit

3. mol L–1s–1

4. s–1

Subtopic:  Order, Molecularity and Mechanism |
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What is the pre-exponential factor for a reaction at 500 K with a rate constant of 0.02 s⁻¹ and an activation energy of 18.230 kJ?


1. 1.61
2. 1.41
3. 1.81
4. 1.21
Subtopic:  Arrhenius Equation |
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The activation energy for the reaction 2HI(g) → H2 + I2(g) is 209.5 kJ mol−1 at 581K.  The fraction of molecules of reactants having energy equal to or greater than activation energy is-

1. 2.67 × 10−19
2. 3.57 × 10−18
3. 4.67 × 10−17
4. 1.47 × 10−19
Subtopic:  Arrhenius Equation |
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Assertion(A): The catalyst can increase that rate constant to a large extent.
Reason(R): By using a suitable catalyst, we can increase the rate of reaction.

1. Both A and R are correct and R is the correct explanation of A.
2. Both A and R are correct but R is not the correct explanation of A.
3. A is true and R is false 
4. A is false and R is true 
Subtopic:  Catalyst |
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Assertion(A): For exothermic reaction equilibrium constant decreases with an increase in temperature.
Reason(R): For a reaction, the rate constant decreases with decrease in temperature.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True and (R) is False 
4. (A) is False and (R) is True 
Subtopic:  Definition, Rate Constant, Rate Law |
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