When the temperature of a reaction increases from 300 K to 310 K, the rate of the reaction doubles. What is the activation energy for this reaction?

 \((R=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1} \text { and } \log 2=0.301)\)

1. \(53.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 2. \(68.6 \mathrm{~kJ} \mathrm{~mol}^{-1} \)
3. \(59.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \) 4. \(70.5 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

Subtopic:  Arrhenius Equation |
 73%
Level 2: 60%+
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For a reaction of the type 2A + B  2C, the rate of the reaction is given by kA2B. When the volume of the reaction vessel is reduced to 14 th of the original volume, the rate of reaction changes by a factor of:

1. 0.25                                                          

2. 16

3. 64                                                             

4. 4

Subtopic:  Definition, Rate Constant, Rate Law | First Order Reaction Kinetics |
 76%
Level 2: 60%+
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If a reaction A + B → C is exothermic to the extent of 30 kJ mol−1 and the forward reaction has an activation energy of 249 kJ mol−1, the activation energy for the reverse reaction in kJ mol-1 will be:

1. 324 2. 279
3. 40 4. 100
Subtopic:  Arrhenius Equation |
 94%
Level 1: 80%+
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Select the correct option based on statements below:

Assertion (A): For elementary reactions, the law of mass action and the rate of law expression are generally the same.
Reason (R): The molecularity of an elementary reaction is always one.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Order, Molecularity and Mechanism |
 67%
Level 2: 60%+
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For a reaction A → B, the Arrhenius equation is given as  \(log_{e}k \ = \ 4 \ - \ \frac{1000}{T}\) the activation energy in J/mol for the given reaction will be:

1. 8314

2. 2000

3. 2814

4. 3412

Subtopic:  Arrhenius Equation |
 77%
Level 2: 60%+
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The rate constant for a first-order reaction is 4.606×10-3 s-1. The time required to reduce 2.0 g of the reactant to 0.2 g will be:

1. 200 s 2. 500 s
3. 1000 s 4. 100 s
Subtopic:  First Order Reaction Kinetics |
 87%
Level 1: 80%+
NEET - 2020
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For the reaction, \(2 A+B \rightarrow 3 C+D\)

Which of the following is an incorrect expression for the rate of reaction?

1. \(-\frac{d[C]}{{3} d t }\) 2. \(-\frac{d[B]}{d t} \)
3. \(\frac{d[D]}{d t} \) 4. \(-\frac{d[A]}{2 d t}\)
Subtopic:  Definition, Rate Constant, Rate Law |
 90%
Level 1: 80%+
AIPMT - 2006
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For a general reaction A  B, the plot of the concentration of A vs. time is given in the figure.
 

The slope of the curve will be:

1. -k 2. -k/2
3. -k2 4. -k/3
Subtopic:  Definition, Rate Constant, Rate Law |
 90%
Level 1: 80%+
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The decomposition of hydrocarbons follows the equation: k = (4.5 × 1011s–1) e28000K/T

The activation energy (Ea) for the reaction would be:
1. 232.79 kJ mol1
2. 245.86 kJ mol1
3. 126.12 kJ mol1
4. 242.51 kJ mol1

Subtopic:  Arrhenius Equation |
 77%
Level 2: 60%+
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The role of a catalyst is to change: 

1. Gibbs energy of the reaction
2. Enthalpy of reaction
3. The activation energy of the reaction 
4. Equilibrium constant
Subtopic:  Catalyst |
 94%
Level 1: 80%+
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