Molar conductivities (°m) at infinite dilution of
NaCl, HCl, and CH3COONa are 126.4, 425.9, and 91.0 S cm2 mol–1 respectively.
 (°m)  for CH3COOH  will be: 

1. \(180.5~S~cm^2~mol^{-1}\) 2. \(290.8~S~cm^2~mol^{-1}\)
3. \(390.5~S~cm^2~mol^{-1}\) 4. \(425.5~S~cm^2~mol^{-1}\)

Subtopic:   Kohlrausch Law & Cell Constant |
 91%
Level 1: 80%+
AIPMT - 2012
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The correct expression that  represents the equivalent conductance at infinite dilution of Al2(SO4)3 is:

(Given that Al3+° and SO42-° are the equivalent conductances at infinite dilution of the respective ions)

1. Al3+° + SO42-°

2. Al3+° + SO42-°×6

3. 13Al3+° +12 SO42-°

4. 2Al3+° +3 SO42-°

Subtopic:  Conductance & Conductivity |
 64%
Level 2: 60%+
AIPMT - 2010
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Consider the following relations for emf of an electrochemical cell:

(a) emf of cell = (Oxidation potential of anode) – (Reduction potential of cathode)
(b) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode)
(c) emf of cell = (Reduction potential of anode) + (Reduction potential of cathode)
(d) emf of cell = (Oxidation potential of anode) – (Oxidation potential of cathode)


Which of the following combinations correctly represents the relation for the emf of the cell?

1. (a) and (b) 2. (c) and (d)
3. (b) and (d) 4. (c) and (a)
Subtopic:  Electrode & Electrode Potential |
 70%
Level 2: 60%+
AIPMT - 2010
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The Gibb's energy for the decomposition of \(\mathrm{A l_{2} O_{3}}\) at \(\mathrm{500~ ^\circ C}\) is as follows: 

2/3Al2O3 → 4/3Al + O2 ; ∆rG = + 960 k J mol–1

The potential difference needed for the electrolytic reduction of aluminium oxide (Al2O3) at \(\mathrm{500~ ^\circ C}\) is at least,

1. 3.0 V 

2. 2.5 V 

3. 5.0 V 

4. 4.5 V 

Subtopic:  Relation between Emf, G, Kc & pH |
 63%
Level 2: 60%+
AIPMT - 2012
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Consider the half-cell reduction reaction:
\(\text{Mn}^{2+}+2e^-\rightarrow \text{Mn},\ E^{0}= -1.18~ \text V \) 
\(\text{Mn}^{2+}\rightarrow \text{Mn}^{3+}+e^-,\ E^{0}= -1.5~ \text V \)

The \(E^{0}\) for the reaction \(\mathrm{3\ Mn^{2+}\rightarrow Mn^{0}+2Mn^{3+} }\) and possibility of the forward reaction are respectively:
 
1. –4.18 V and Yes 2. +0.33 V and Yes
3. +2.69 V and No 4. –2.69 V and No
Subtopic:  Electrode & Electrode Potential |
 55%
Level 3: 35%-60%
NEET - 2013
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How many grams of cobalt metal will be deposited when a solution of cobalt (II) chloride is electrolyzed with a current of 10 amperes for 109 minutes?
(Given: 1 Faraday = 96,500 C; Atomic mass of Co = 59 u)
1. 4.0 2. 20.0
3. 40.0 4. 0.66
Subtopic:  Faraday’s Law of Electrolysis |
 71%
Level 2: 60%+
NEET - 2013
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A hypothetical electrochemical cell is shown below.
A|A+(x M) || B+(y M)|B
The Emf measured is +0.20 V. The cell reaction is:

1. A+ + B → A + B+

2.  A+ + e- → A ; B+ + e- → B

3. The cell reaction cannot be predicted.

4. A + B+ → A+ + B

Subtopic:  Electrochemical Series | Nernst Equation |
 76%
Level 2: 60%+
AIPMT - 2006
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If EFe2+/Feo = -0.441 V and  EFe3+/Fe2+o = 0.771 V, the standard emf of the reaction: 

Fe + 2Fe3+→ 3Fe2+ will be:

1. 0.330 V 2. 1.653 V
3. 1.212 V 4. 0.111 V
Subtopic:  Electrode & Electrode Potential |
 74%
Level 2: 60%+
AIPMT - 2006
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In producing chlorine through electrolysis, 100 W power at 125 V is being consumed.
The liberation of chlorine per min is:
(ECE of chlorine is 0.367×10-6 kg/C)
1. 17.6 mg 2. 21.3 mg
3. 24.3 mg 4. 13.6 mg
Subtopic:  Faraday’s Law of Electrolysis |
 63%
Level 2: 60%+
AIPMT - 2006
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The efficiency of a fuel cell is given by:

1. HG

2. GS

3. GH

4. SG

Subtopic:  Batteries & Salt Bridge |
 66%
Level 2: 60%+
AIPMT - 2007
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