# The molar conductance of NaCl, HCI, and CH3COONa at infinite dilution are 126.45, 426.16, and 91.0 S cm mol-1 respectively. The molar conductance of CH3COOH at infinite dilution will be: 1. 698.28 S cm2 mol-1 2. 540.48 S cm2 mol-1 3. 201.28 S cm2 mol-1 4. 390.71 S cm2 mol-1

Subtopic:   Kohlrausch Law & Cell Constant |
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NEET - 2021
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The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol-1. The dissociation constant of acetic acid is -

($$\mathrm{\Lambda_{H^{+}}^{o} \ = \ 350 \ S \ cm^{2} \ mol^{-1} }$$)
($$\mathrm{\mathrm{\Lambda_{CH_{3}COO^{-}}^{o} \ = \ 50 \ S \ cm^{2} \ mol^{-1} }}$$)

1. $1.75×{10}^{-5}$ mol L-1

2. $2.50×{10}^{-5}$ mol L-1

3. $1.75×{10}^{-4}$ mol L-1

4. $2.50×{10}^{-4}$ mol L-1

Subtopic:   Kohlrausch Law & Cell Constant |
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NEET - 2021
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In a typical fuel cell, the reactants (R) and products (P) are:

 1 R = H2(g), O2(g); P = H2O2(l) 2 R = H2(g), O2(g); P = H2O(l) 3 R = H2(g) , O2(g) , C l2(g) ;   P = HClO4(aq) 4 R = H2(g) , N2(g) ;  P = NH3(aq)

Subtopic:  Batteries & Salt Bridge |
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NEET - 2020
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Given below are half-cell reactions:
$$\mathrm{MnO}_{4}^{-}+8 \mathrm{H}^{+}+5 \mathrm{e}^{-} \rightarrow \mathrm{Mn}^{2+}+4 \mathrm{H}_{2} \mathrm{O},$$
$$\mathrm{E}_{\mathrm{Mn}^{2+}}^{\circ} / \mathrm{MnO}_{4}^{-}=-1.510 \mathrm{~V}$$
$$\frac{1}{2} \mathrm{O}_{2}+2 \mathrm{H}^{+}+2 \mathrm{e}^{-} \rightarrow \mathrm{H}_{2} \mathrm{O},$$
$$\mathrm{E}_{\mathrm{O}_{2} / \mathrm{H}_{2} \mathrm{O}}^{\circ}=+1.223 \mathrm{~V}$$
Will the permanganate ion, $$\mathrm{MnO}_{4}^{-}$$ , liberate $$\mathrm{O}_{2}$$ from water in the presence of an acid?

1. No, because $$\mathrm{E}_{\text {cell }}^{\circ}=-2.733 \mathrm{~V}$$
2. Yes, because $$\mathrm{E}_{\text {cell }}^{\circ}=+0.287 \mathrm{~V}$$
3. No, because $$\mathrm{E}_{\text {cell }}^{\circ}=-0.287 \mathrm{~V}$$
4. Yes, because $$\mathrm{E}_{\text {cell }}^{\circ}=+2.733 \mathrm{~V}$$
Subtopic:  Electrode & Electrode Potential |
From NCERT
NEET - 2022
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Find the emf of the cell in which the following reaction takes place at 298 K:
$$\mathrm{Ni}(\mathrm{s})+2 \mathrm{Ag}^{+}(0.001 \mathrm{M}) \rightarrow \mathrm{Ni}^{2+}(0.001 \mathrm{M})+2 \mathrm{Ag}(\mathrm{s})$$
$$\small{\text { (Given that } \mathrm{E}_{\text {cell }}^{\circ}=10.5 \mathrm{~V}, \frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.059 \text { at } \ 298 \mathrm{~K})}$$
1. 1.05 V
2. 1.0385 V
3. 1.385 V
4. 0.9615 V

Subtopic:  Nernst Equation |
From NCERT
NEET - 2022
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The three cells with their $$E^\circ_{\text{(cell)}}$$ values are given below:

 Cells $$E^\circ_{\text{(cell)}}/V$$ (a) Fe|Fe2+||Fe3+|Fe 0.404 (b) Fe|Fe2+||Fe3+, Fe2+|Pt 1.211 (c) Fe|Fe3+||Fe3+, Fe2+|Pt 0.807
The standard Gibbs free energy change values for three cells are, respectively
(F represents the charge on 1 mole of electrons.)

 1 -1.212 F, -1.211 F, -0.807 F 2 +2.424 F, +2.422 F, +2.421 F 3 -0.808 F, -2.422 F, -2.421 F 4 -2.424 F, -2.422 F, -2.421 F
Subtopic:  Faraday’s Law of Electrolysis |
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NEET - 2022
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$$\land^o_m$$ for NaCl, HCl and $$CH_3COONa$$ are 126.4, 425.9, and 91.05 S cm2 mol-1 respectively. If the conductivity of 0.001028 mol L-1 acetic acid solution is $$4.95 \times 10^{-5} S ~cm^{-1}$$, the degree of dissociation of the acetic acid solution is-

 1 0.01233 2 1 3 0.1233 4 1.233
Subtopic:  Conductance & Conductivity |
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Two half cell reactions are given below:
\begin{aligned} &\mathrm{Co}^{3+}+e^{-} \rightarrow \mathrm{Co}^{2+}, \mathrm{E}_{\mathrm{Co}^{2+} / \mathrm{Co}^{3+}}^{\circ}=-1.81 \mathrm{~V} \\ &2 \mathrm{Al}^{3+}+6 e^{-} \rightarrow 2 \mathrm{Al}(\mathrm{s}), \mathrm{E}_{\mathrm{Al} / \mathrm{Al}^{3+}}^{\circ}=+1.66 \mathrm{~V} \end{aligned}
The standard EMF of a cell with feasible redox reaction will be:

 1 +7.09 V 2 +0.15 V 3 +3.47 V 4 –3.47 V
Subtopic:  Electrode & Electrode Potential |
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NEET - 2022
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Standard electrode potential for the cell with cell reaction
Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)
is 1.1 V. Calculate the standard Gibbs energy change for the cell reaction.
(Given F = 96487 C mol-1)
 1 -200.27 kJ mol-1 2 -212.27 kJ mol-1 3 -212.27 J mol-1 4 -200.27 J mol-1
Subtopic:  Relation between Emf, G, Kc & pH |
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NEET - 2022
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Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R):
 Assertion (A): In equation $$\Delta_{\mathrm{r}} \mathrm{G}=-\mathrm{nFE} _{\text {cell }},$$ value $$\Delta_rG$$ depends on n. Reason (R): $$E_{cell}$$ is an intensive property and  $$\Delta_rG$$  is an extensive property.

In the light of the above statements choose the correct answer from the options given below:

 1 (A) is false but (R) is true. 2 Both (A) and (R) are true and (R) is the correct explanation of (A). 3 Both (A) and (R) are true and (R) is NOT the correct explanation of (A). 4 (A) is true but (R) is false.
Subtopic:  Relation between Emf, G, Kc & pH |
56%
From NCERT
NEET - 2023