In comparison to a 0.01 M solution of glucose, the depression in the freezing point of a 0.01 M MgCl2 solution will be:
| 1. | Same | 2. | About twice |
| 3. | About three times | 4. | About six times |
The incorrect statement among the following is:
| 1. | Two different solutions of sucrose of the same molality prepared in different solvents will have the same depression in freezing point. |
| 2. | The osmotic pressure of a solution is given by the equation π = CRT (where C is the molarity of the solution) |
| 3. | Decreasing order of osmotic pressure for 0.01 M aqueous solutions of BaCl2 > KCl > CH3COOH > sucrose |
| 4. | The vapour pressure exerted by a volatile component of a solution is directly proportional to its mole fraction in the solution. |
Match the laws/colligative properties given in Column-I with expressions given in Column-II.
| Column-I | Column-II | ||
| A. | Raoult’s law | I. | \(\mathrm{\pi=C R T}\) |
| B. | Osmotic pressure | II. | \(\Delta \mathrm{T}_{\mathrm{f}}=\mathrm{K}_{\mathrm{f}} \mathrm{~m}\) |
| C. | Elevation of boiling point | III. | \(\mathrm{p=x_1 p_1^0+x_2 p_2^0}\) |
| D. | Depression in freezing point | IV. | \(\Delta \mathrm{T}_{\mathrm{b}}=\mathrm{K}_{\mathrm{b}} \mathrm{~m}\) |
Codes:
| A | B | C | D | |
| 1. | I | III | IV | I |
| 2. | I | II | III | IV |
| 3. | I | IV | III | II |
| 4. | III | I | IV | II |
Select the correct option based on statements below:
| Assertion (A): | When NaCl is added to water a depression in freezing point is observed. |
| Reason (R): | The lowering of vapour pressure of a solution causes depression in the freezing point. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |