Assertion (A): | 2-butyne on controlled hydrogenation with Pd/CaCO3 (Lindlar's catalyst) in presence of PbO gives cis 2-butene. |
Reason (R): | Hydrogenation occurs at the surfaces of metal-containing adsorbed hydrogen. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | Alkanes having more than three carbon atoms exhibit chain isomerism. |
Reason (R): | All carbon atoms in alkanes are \(sp\)-hybridized. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Alkenes and series of cycloalkanes of hydrocarbons have the same general formula. |
Reason (R): | Either insertion of a double bond or formation of a ring reduces the number of hydrogen atoms of the corresponding alkane by 2. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | 2-Bromobutane, in reaction with sodium ethoxide in ethanol, gives 1-butene as a major product. |
Reason (R): | 1-Butene is more stable than 2-butene. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | The addition of HBr on 2-butene gives two isomeric products. |
Reason (R): | The addition of HBr on 2-butene follows Markovnikov's rule. |
1. | Both (A) and (R) are True and (R) correctly explains (A). |
2. | Both (A) and (R) are True but (R) does not correctly explain (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Propene reacts with HBr in the presence of H2O2 to give Markovnikov's addition product. |
Reason (R): | H2O2 forms free radicals which cause homolytic cleavage of H-Br. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Trans-but-2-ene has a higher boiling point than cis-but-2-ene. |
Reason (R): | Trans-but-2-ene is more polar than cis-but-2-ene. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Statement I: | Treatment of 1,2-dibromopropane with zinc produces cyclopropane. |
Statement II: | The reaction of alkyl halides with any metal is called a substitution reaction. |
1. | Statement I is incorrect and Statement II is correct. |
2. | Both Statement I and Statement II are correct. |
3. | Statement I is correct and Statement II is incorrect. |
4. | Both Statement I and Statement II are incorrect. |