Select the correct option based on statements below:
Assertion (A): 2-butyne on controlled hydrogenation with Pd/CaCO3 (Lindlar's catalyst) in presence of PbO gives cis 2-butene.
Reason (R): Hydrogenation occurs at the surfaces of metal-containing adsorbed hydrogen.
  
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.
Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 55%
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Given below are two statements:  
Assertion (A): Alkanes having more than three carbon atoms exhibit chain isomerism.
Reason (R): All carbon atoms in alkanes are \(sp\)-hybridized.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
Subtopic:  Aliphatic Hydrocarbon -Nomenclature, Isomerism & Mechanism |
 85%
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Given below are two statements: 
Assertion (A): Alkenes and series of cycloalkanes of hydrocarbons have the same general formula.
Reason (R): Either insertion of a double bond or formation of a ring reduces the number of hydrogen atoms of the corresponding alkane by 2.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

 
Subtopic:  Aliphatic Hydrocarbon -Nomenclature, Isomerism & Mechanism |
 78%
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Assertion (A): 2-Bromobutane, in reaction with sodium ethoxide in ethanol, gives 1-butene as a major product.
Reason (R): 1-Butene is more stable than 2-butene.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 66%
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Consider the given two statements:
Assertion (A): The addition of HBr on 2-butene gives two isomeric products.
Reason (R): The addition of HBr on 2-butene follows Markovnikov's rule.
 
1. Both (A) and (R) are True and (R) correctly explains (A).
2. Both (A) and (R) are True but (R) does not correctly explain (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
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Assertion(A): Alkyl benzene is not prepared by Friedel-Crafts alkylation of benzene.
Reason(R): Alkyl halides are less reactive than acyl halides.
1. Both A and R are true and R is the correct explanation of A.
2. Both A and R are true but R is not the correct explanation of A.
3. A is true but R is false.
4. Both A and R are false statements.
Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions |
 70%
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Assertion(A): \(CH\equiv C-CH_2-CH=CH_2\) adds up HBr to give \(CH\equiv C-CH_2-CH-CH_3\\ ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~|\\ ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~Br \) while \(CH\equiv C-CH=CH_2\) adds HBr to give \(CH_2= C-CH=CH_2\\ ~~~~~~~~~~~~~~|\\ ~~~~~~~~~~~~~Br\) .
Reason(R): Double bond is more reactive than triple bond towards electrophilic \(\)addition reaction.

1. Both A and R are true and R is the correct explanation of A.
2. Both A and R are true but R is not the correct explanation of A.
3. A is true but R is false.
4. Both A and R are false statements.
Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
 52%
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Consider the given two statements:
Assertion (A): Propene reacts with HBr in the presence of H2O2 to give Markovnikov's addition product.
Reason (R): H2Oforms free radicals which cause homolytic cleavage of H-Br.
Select the correct option:
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
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Assertion (A): Trans-but-2-ene has a higher boiling point than cis-but-2-ene.
Reason (R): Trans-but-2-ene is more polar than cis-but-2-ene.
  
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
Subtopic:  Aliphatic Hydrocarbon- Physical Properties |
 59%
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Given below are two statements:
Statement I: Treatment of 1,2-dibromopropane with zinc produces cyclopropane.
Statement II: The reaction of alkyl halides with any metal is called a substitution reaction.
 
1. Statement I is incorrect and Statement II is correct.
2. Both Statement I and Statement II are correct.
3. Statement I is correct and Statement II is incorrect.
4. Both Statement I and Statement II are incorrect.
Subtopic:  Aliphatic Hydrocarbon- Physical Properties |
 55%
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