The B–F bond lengths in ${\mathrm{BF}}_3$ (130 pm) and $\mathrm{B}{{\mathrm{F}}_4}^{-}$(143 pm) differ because of:

1. Presence of triple bond character in ${\mathrm{BF}}_3$

2. Resonance in $\mathrm{B}{{\mathrm{F}}_4}^{-}$

3. Presence of a double bond character in ${\mathrm{BF}}_3$

4. Presence of a double bond character in $\mathrm{B}{{\mathrm{F}}_4}^{-}$

Despite the dipole moment in the B–Cl bond, the BCl₃ molecule as a whole has no dipole moment because:

CO is a poisonous gas because :

An excessive content of CO₂ is responsible for global warming as:

The sharp decrease in ionization enthalpy from carbon to silicon happens because of-

The correct explanation for the lower atomic radius of Ga as compared to Al is -

1. Poor shielding effect of the 2d-electrons

2. Poor shielding effect of the 3d-electrons

3. Poor shielding effect of the 3p-electrons

4. Poor shielding effect of the 2s-electrons

Amphoteric oxides are:

1. Tl₂O₃, SiO₂

2. ${\mathrm{CO}}_2$, ${\mathrm{B}}_2{\mathrm{O}}_3$

3. ${\mathrm{B}}_2{\mathrm{O}}_3$, ${\mathrm{SiO}}_2$

4. Al₂O₃ , PbO₂

When a metal X is treated with sodium hydroxide, a white precipitate (A) is obtained, which is soluble in excess of NaOH to give soluble complex (B). Compound (A) is soluble in dilute HCl and forms compound (C). The compound (A) when heated strongly gives (D), which is used to extract the metal.

X, C & D are respectively :

An aqueous solution of Borax is-

Boric acid is polymeric due to-

1. Its acidic nature.

2. The presence of hydrogen bonds.

3. Its monobasic nature.

4. Its geometry.