The oxidation states of the central atom in the given species are, respectively:

${\mathrm{H}}_4{\mathrm{P}}_2{\mathrm{O}}_7$ $$ $\mathrm{and}$ ${\mathrm{H}}_2{\mathrm{S}}_2{\mathrm{O}}_7$

KI₃, H₂S₄O₆

The oxidation numbers of iodine and sulphur in the above compounds are, respectively:

1. \(\dfrac{1}{3}\) ; 4
2. 2.5 ; \(\dfrac{1}{3}\)
3. \(-\dfrac{1}{3}\) ; 2.5
4. 2.5 ; 3

Which of the following reactions does not involve disproportionation process?

1. ${\mathrm{Cl}}_2+{\mathrm{OH}}^{-}\to {\mathrm{Cl}}^{-}+{\mathrm{ClO}}_3^{-}+{\mathrm{H}}_2\mathrm{O}$

2. $2{\mathrm{H}}_2{\mathrm{O}}_2\to {\mathrm{H}}_2\mathrm{O}+{\mathrm{O}}_2$

3. $2{\mathrm{Cu}}^{+}\to {\mathrm{Cu}}^{2+}+\mathrm{Cu}$

4. ${\left({\mathrm{NH}}_4\right)}_{2}C{r}_2{O}_7\to {\mathrm{N}}_2+{\mathrm{Cr}}_2{\mathrm{O}}_3+4{\mathrm{H}}_2\mathrm{O}$

Which of the following reactions does not represent a redox change?

1. CaCO₃ $\to$CaO + CO₂

2. 2H₂ + O₂ $\to$2H₂O

3. Na + H₂O $\to$ NaOH + \(\frac{1}{2}\)H₂

4. MnCl₃ $\to$ MnCl₂ + \(\frac{1}{2}\)Cl₂

Fluorine reacts with ice as per the following reaction

H₂O(s) + F₂(g) → HF(g) + HOF(g)

This reaction is a redox reaction because-

The formulas for the following compounds are: 

(a) Mercury(II) chloride  and (b) Thallium(I) sulphate

1. HgCl₂,  Tl₂SO₄

2. Hg₂Cl₂, Tl₂SO₄

3. HgCl₂,  TlSO₄

4. HgCl₂,  Tl₃SO₄

The correct statement(s) about the given reaction is -

\(\small\mathrm{{X} eO_{6 (aq)}^{4 -} + 2 F^{- 1}_{(aq)} + 6 H^{+}_{(aq )} \rightarrow}~\mathrm{{X} eO_{3 (g)} + {F}_{2 (g)} + 3 H_{2} O_{(l)}}\)${}_{}$

1. ${\mathrm{XeO}}_6^{4-}$ oxidises F^-

2. The oxidation number of F increases from -1  to  zero

3. ${\mathrm{XeO}}_6^{4-}$ is a stronger oxidizing agent that ${\mathrm{F}}^{-}$

4. All of the above