Given below are two statements:
Assertion (A): | The ionisation of hydrogen sulphide in water is low in the presence of hydrochloric acid. |
Reason (R): | Hydrogen sulphide is a weak acid. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | For any chemical reaction at a particular temperature, the equilibrium constant is fixed and is a characteristic property. |
Reason (R): | Equilibrium constant is independent of temperature. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | An aqueous solution of ammonium carbonate is basic. |
Reason (R): |
The acidic or basic nature of a salt solution of a salt of a weak acid and a weak base depends on the Ka and Kb values of the acid and the base forming it. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | An aqueous solution of ammonium acetate can act as a buffer. |
Reason (R): | Acetic acid is a weak acid and NH4OH is a weak base. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | In the dissociation of PCl5 at constant pressure and temperature, the addition of helium at equilibrium increases the dissociation of PCl5. |
Reason (R): | Helium reacts with Cl2 . |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
The value of for the following reaction will be :
1. | 1 | 2. | 0.5 |
3. | 1.5 | 4. | 2 |
For the reaction , the standard free energy is . The equilibrium constant () would be :
1. | \(K_{c}\)=0 | 2. | \(K_{c}\)>1 |
3. | \(K_{c}\)=1 | 4. | \(K_{c}\)<1 |
1. | Equilibrium is possible only in a closed system at a given temperature. |
2. | All measurable properties of the system remain constant. |
3. | All the physical processes stop at equilibrium. |
4. | The opposing processes occur at the same rate and there is a dynamic but stable condition. |
PCl5, PCl3, and Cl2 are at equilibrium at 500 K in a closed container and their concentrations are 0.8×10–3 mol L–1 , 1.2×10–3 mol L–1 and 1.2×10–3 mol L–1, respectively.
The value of Kc for the reaction PCl5(g) ⇌ PCl3(g) + Cl2(g) will be:
1. 1.8 × 103 mol L–1
2. 1.8 × 103
3. 1.8 × 10–3 mol L–1
4. 0.55 × 104
An incorrect statement about equilibrium among the following is:
1. | In equilibrium mixture of ice and water kept in perfectly insulated flask, the mass of ice and water does not change with time. |
2. | The intensity of the red colour increases when oxalic acid is added to a solution containing iron (III) nitrate and potassium thiocyanate. |
3. | On the addition of a catalyst, the equilibrium constant value is not affected. |
4. | The equilibrium constant for a reaction with a negative ∆H value decreases as the temperature increases. |