Match Column-I with Column-II and mark the appropriate option:
Column-I (Term) |
Column-II (Conditions) |
||
(A) |
Equilibrium |
(i) | |
(B) |
Spontaneous reaction |
(ii) | |
(C) |
Non-spontaneous reaction |
(iii) |
Codes:
Options: | A | B | C |
1. | (ii) | (iii) | (i) |
2. | (i) | (ii) | (iii) |
3. | (ii) | (i) | (iii) |
4. | (iii) | (i) | (ii) |
Given below are two statements:
Assertion (A): | The increasing order or acidity of hydrogen halides is HF<HCI<HBr<HI. |
Reason (R): | While comparing acids formed by the elements belonging to the same group of the periodic table, H-A bond strength is a more important factor in determining the acidity of an acid than the polar nature of the bond. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | A solution containing a mixture of acetic acid and sodium acetate maintains a constant value of pH on the addition of small amounts of acid or alkali. |
Reason (R): | A solution containing a mixture of acetic acid and sodium acetate acts as a buffer solution. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | The ionisation of hydrogen sulphide in water is low in the presence of hydrochloric acid. |
Reason (R): | Hydrogen sulphide is a weak acid. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | For any chemical reaction at a particular temperature, the equilibrium constant is fixed and is a characteristic property. |
Reason (R): | Equilibrium constant is independent of temperature. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | An aqueous solution of ammonium carbonate is basic. |
Reason (R): |
The acidic or basic nature of a salt solution of a salt of a weak acid and a weak base depends on the Ka and Kb values of the acid and the base forming it. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | An aqueous solution of ammonium acetate can act as a buffer. |
Reason (R): | Acetic acid is a weak acid and NH4OH is a weak base. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Given below are two statements:
Assertion (A): | In the dissociation of PCl5 at constant pressure and temperature, the addition of helium at equilibrium increases the dissociation of PCl5. |
Reason (R): | Helium reacts with Cl2 . |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
The value of for the following reaction will be :
1. | 1 | 2. | 0.5 |
3. | 1.5 | 4. | 2 |
For the reaction , the standard free energy is . The equilibrium constant () would be :
1. | \(K_{c}\)=0 | 2. | \(K_{c}\)>1 |
3. | \(K_{c}\)=1 | 4. | \(K_{c}\)<1 |