If the equilibrium constant for AB+CisKeq(1) and that of BCPisKeq(2), the equilibrium constant for AP is: 

1. Keq(2)-Keq(1)

2. Keq(1×Keq(2)

3. Keq(1)+Keq(2)

4. Keq(2)/Keq(1)

Subtopic:  Kp, Kc & Factors Affecting them |
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The correct expression for the following reaction is:

Fe2N(s) + \(\frac{3}{2}\)H2(g) \(\leftrightharpoons \) 2Fe(s) + NH3(g)

1. Kc=Kp(RT)

2. Kc=Kp(RT)-3/2

3. Kc=Kp(RT)-1/2

4. Kc=Kp(RT)1/2

Subtopic:  Kp, Kc & Factors Affecting them |
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For the reaction, 2SO2(g) + O2(g) = 2SO3(g), H = –57.2 kJ mol–1 and KC = 1.7 × 1016 .
Which of the following statements is incorrect?

1.  The equilibrium will shift in the forward direction as the pressure increases.
2.  The addition of inert gas at constant volume will not affect the equilibrium constant.
3.  The equilibrium constant is large suggestive of the reaction going to completion and so no catalyst is required.
4.  The equilibrium constant decreases as the temperature increases.

Subtopic:  Kp, Kc & Factors Affecting them |
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In which one of the following equilibria, Kp \(\ne\) KC?

1. 2NO(g)N2(g)+O2(g)

2. 2C(s)+O2(g)2CO(g)

3. 2HI(g)H2(g)+I2(g)

4. NO2(g)+SO2(g)NO(g)+SO3(g)

Subtopic:  Kp, Kc & Factors Affecting them |
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The standard Gibbs energy change at 300 K for the reaction 2AB+C is 2494.2 J. At a given time, the composition of the reaction mixture is A=12,B=2andC=12. The reaction proceeds in the:[assume R=8.314 J/K/mol; e-1 = 0.37]

1. Forward direction because Q > KC
2. Reverse direction because Q >  KC
3. Forward direction because Q <  KC
4. Reverse direction because Q <  KC

Subtopic:  Kp, Kc & Factors Affecting them |
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The equilibrium constant (Kc) for the reaction N2(g) + O2(g) → 2NO(g) at temperature T is 4 × 10–4.
The value of Kc for the reaction, 
NO(g)12N2(g)+12O2(g) is:

1. 2.5 × 102

2. 4 × 10–4

3. 50.0

4. 0.02

Subtopic:  Kp, Kc & Factors Affecting them |
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The first and second dissociation constants of an acid H2A are 1.0 × 10–5 & 5.0 × 10–10 respectively. The overall dissociation constant of the acid will be :

1. 5.0 × 10–5 2. 5.0 × 1015
3. 5.0 × 10–15 4. 0.2 × 105
Subtopic:  Kp, Kc & Factors Affecting them |
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The equilibrium constant for the reaction
\(\mathrm{N}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{NO}(g)\)
at temperature T is \(4 \times 10^{-4}\) . The value of Kc for the reaction,
\(\mathrm{{NO}}(g) \rightleftharpoons \frac{1}{2} \mathrm{{~N}_{2}}(g)+\frac{1}{2} \mathrm{O}_{2}(g)\)at the same temperature) is :

1. \(2.5 \times 10^{2}\)

2. \(5 \times 10^{1}\)

3. \(4 \times 10^{-4}\)

4. \(2 \times 10^{-2}\)

Subtopic:  Kp, Kc & Factors Affecting them |
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For a hypothetical reaction
A ⇋ B ; Keq = 102
(Use T = 27 °C, R = 8.3 JK−1mol−1, ln10 = 2.3)
If the value of ∆G° for the above reaction is −x kJ, the value of 2x will be: 
(Round off to the nearest integer)

1. 11
2. 19
3. 23
4. 28
Subtopic:  Kp, Kc & Factors Affecting them |
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Consider the following equilibrium reaction:
\(\mathrm{H}_2+\mathrm{I}_2 \rightleftharpoons 2 \mathrm{HI}\)
At equilibrium, if the number of molecules of  \(\mathrm{H}_2,~ \mathrm{I}_2,\) and \(\mathrm{HI}\) are equal, and the equilibrium constant \(\mathrm{K}_{\mathrm{p}}=\mathrm{t} \times 10^{-1}\), the value of t is:
1. 10.0 2. 0.01
3. 0.10 4. 1.0
Subtopic:  Kp, Kc & Factors Affecting them |
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