Assertion (A): | For an isothermal physical process, the change in internal energy is equal to zero. |
Reason (R): | The internal energy is directly proportional to temperature for physical processes. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | The increase in internal energy \((\Delta E ) \) for the vapourisation of one mole of water at 1 atm and 373 K is zero. |
Reason (R): | For all isothermal processes, \(\Delta E = 0 \). |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True and (R) is False. |
4. | (A) and (R) both are False. |
Assertion (A): | Absolute values of the internal energy of substances cannot be determined. |
Reason (R): | It is impossible to determine the exact values of constituent energies of the substances. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | ∆H is positive for endothermic reactions. |
Reason (R): | If the total enthalpy of reactants and products are Hr & Hp respectively, then for an endothermic reaction HR < HP. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Assertion (A): | Cdiamond → Cgraphite ∆H and ∆U are the same for this reaction. |
Reason (R): | Entropy increases during the conversion of diamond to graphite. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
For one mole of an ideal gas, which of these statements must be true?
(I) U and H each depend only on temperature.
(II) Compressibility factor z is not equal to 1.
(III) CP, m – CV, m = R
(IV) dU = CVdT for any process.
1. (I), (III) and (IV)
2. (II), (III) and (IV)
3. (III) and (IV)
4. (I) and (III)
Consider the following diagram for a reaction .
The nature of the reaction is-
1. Exothermic
2. Endothermic
3. Reaction at equilibrium
4. None of the above
What is the nature of the reaction depicted in the given diagram for A→C?
1. | Exothermic | 2. | Endothermic |
3. | Reaction at equilibrium | 4. | None of these |