Match the following process with entropy change

Reaction Entropy change
A. A liquid vaporizes 1. S=0
B. Reaction is non-spontaneous at all temperatures and H is positive 2. S=positive
C. Reversible expansion of an ideal gas 3. S=negative

Codes

A B C
1. 2 3 1
2. 1 2 3
3. 1 3 2
4. 3 2 1
Subtopic:  Spontaneity & Entropy |
 80%
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Match the following parameters with a description for spontaneity.

\(\Delta\) (Parameters) \(\Delta r\ H^⊝\) \(\Delta r\ S^⊝\)\(\Delta r\ G^⊝\) Description
A. + - + 1. Non-spontaneous at high temperature
B. - - + at high T 2. Spontaneous at all temperatures
C. - + - 3. Non-spontaneous at all temperatures

Codes

A B C
1. 3 1 2
2. 1 2 3
3. 1 3 2
4. 3 2 1
Subtopic:  Spontaneity & Entropy |
 75%
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Match the statements given in column 1 with corresponding characteristics given in column II and choose the correct option:

Column -I Column -II
A. Entropy of vaporization 1. Decreases
B. K for a spontaneous process 2. Is always positive
C. Crystalline solid state 3. Lowest entropy
D. \(\Delta U\) in an adiabatic expansion of ideal gas 4. \(\Delta H_{vap} \over T_b\)


Codes

Options: A B C D
1. 2,4 2 3 1
2. 1 2 3 4
3. 1 4,3 3 2
4. 4 3 3,1 2
Subtopic:  Spontaneity & Entropy | Gibbs Energy Change |
 79%
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Select the correct option based on statements below:
Assertion (A):   Spontaneous process is an irreversible process and may be reversed by some external agency.
Reason (R):  A decrease in enthalpy is a contributing factor to spontaneity.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.
Subtopic:  Spontaneity & Entropy |
 57%
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Select the correct option based on statements below:
Assertion (A):  A liquid crystallizes into a solid and is accompanied by a decrease in entropy.
Reason (R):  In crystals, molecules organize in an ordered manner.
 
1.  Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.
Subtopic:  Spontaneity & Entropy |
 81%
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The entropy change can be calculated by using the expression S=qrevT. When water freezes in a glass beaker, the correct statement among the following is:

1. ∆ S  (system) decreases but  ∆ S  (surroundings) remains the same
2. ∆ S  (system) increases but  ∆ S  (surroundings) decreases
3. ∆ S  (system) decreases but  ∆ S  (surroundings) increases
4. ∆ S  (system) decreases but  ∆ S  (surroundings) also decreases

Subtopic:  Spontaneity & Entropy |
 60%
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Which of the following is not correct?

1. G is zero for a reversible reaction.

2. G is positive for a spontaneous reaction.

3. G is negative for a spontaneous reaction.

4. G is positive for a non-spontaneous reaction.

Subtopic:  Spontaneity & Entropy |
 82%
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The processes among the following that occur spontaneously are -

a. The flow of heat from a colder to a warmer body.
b. Gas in a container contracting into one corner.
c. Gas expanding to fill the available volume.
d. Burning carbon in oxygen to give carbon dioxide.


1. (a, b)

2. (b, c)

3. (c, d)

4. (a, d)

Subtopic:  Spontaneity & Entropy |
 76%
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