The heat of combustion of carbon to CO₂ is –393.5 KJ/mol. The heat released upon the formation of 35.2 g of CO₂ from carbon and oxygen gas is:
1. –315 KJ
2. +315 KJ
3. –630 KJ
4. +630 KJ

The correct statement for a reversible process in a state of equilibrium is:
1. $∆$G = – 2.30RT log K
2. $∆$G = 2.30RT log K
3. $∆$G^o = – 2.30RT log K
4. $∆$G^o = 2.30RT log K

For the reaction:
\(\mathrm{X}_2 \mathrm{O}_4(l) \rightarrow 2 \mathrm{XO}_2(g)\)
with the given values \(\Delta U = 2.1 \, \text{kcal}\) and \(\Delta S = 20 \, \text{cal K}^{-1}\) at \(300 \, \text{K}\), what is the value of \(\Delta G\)?

1. 2.7 kcal
2. –2.7 kcal
3. 9.3 kcal
4. –9.3 kcal

In which of the following reactions, the standard reaction entropy change
$(∆S^0)$ is positive, and standard Gibb's energy change
$(∆G^0)$ decreases sharply with increasing temperature?

The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 ^oC is:

1. 10.52 cal/(mol K)

2. 21.04 cal/(mol K)

3. 5.260 cal/(mol K)

4. 0.526 cal/(mol K)

The standard enthalpy of vaporization ${∆}_{\mathrm{vap}}{\mathrm{H}}^{\mathrm{o}}$ for water at 100 ^oC is 40.66 kJ mol^–1. The internal energy of vaporization of water at 100 ^oC (in kJ mol^–1) is: 
(Assume water vapour behaves like an ideal gas.)

1. +37.56

2. –43.76

3. +43.76

4. +40.66

Identify which of the following is the correct option for free expansion of an ideal gas under adiabatic condition.

1.  $\mathrm{ \Delta q}\ne 0,$ $∆\mathrm{T}=0,$ $\mathrm{W}=0$
2.  $\mathrm{ \Delta q}=0,$ $∆\mathrm{T}=0,$ $\mathrm{W}=0$
3.  $\mathrm{ \Delta q}=0,$ $∆\mathrm{T}<0,$ $\mathrm{W}\ne 0$
4.  $\mathrm{ \Delta q}=0,$ $∆\mathrm{T}\ne 0,$ $\mathrm{W}=0$

Given the following reaction:
\(4H(g)\)→  \(2 H_{2}\)\((g)\)
The enthalpy change for the reaction is -869.6 kJ. The dissociation energy of the H-H bond is:
1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

Standard entropies of X₂, Y₂ and XY₃ are 60, 40 and 50JK^-1mol^-1 respectively. For the reaction 
$\frac{1}{2}{\mathrm{X}}_2$ $+$ $\frac{3}{2}{\mathrm{Y}}_2$ $$ $\leftrightharpoons$ ${\mathrm{XY}}_3$ $;$ $∆\mathrm{H}$ $=$ $-30$ $\mathrm{kJ}$ to be at equilibrium, the temperature should be:

1. 750 K

2. 1000 K

3. 1250 K

4. 500 K