The amount of heat needed to raise the temperature of 60.0 g of aluminium from 35°C to 55°C would be:

(Molar heat capacity of Al is \(24\) \(J\) \(\text{mol}^{- 1}\) \(K^{- 1}\))

1.	\(1 . 07\) \(J\)	2.	\(1 . 07\) \(kJ\)
3.	\(106 . 7\) \(kJ\)	4.	\(100 . 7\) \(kJ\)

The enthalpy of formation of ${\mathrm{CO}}_{\left(\mathrm{g}\right)},$ ${\mathrm{CO}}_{2\left(\mathrm{g}\right)},$ ${\mathrm{N}}_2{\mathrm{O}}_{\left(\mathrm{g}\right)},\hspace{0.17em}\mathrm{and}$ ${\mathrm{N}}_2{\mathrm{O}}_{4\left(\mathrm{g}\right)}$ $$are –110 kJ ${\mathrm{mol}}^{-1}$, – 393 kJ ${\mathrm{mol}}^{-1}$, 81 kJ ${\mathrm{mol}}^{-\mathrm{1,}}$ and 9.7 kJ \(\text{mol}^{- 1}\) respectively. The value of \(\left(\Delta\right)_{r} H\) for the following reaction would be:

\(\mathrm{N_{2} O_{4 \left(g\right)} + 3 CO{\left(g\right)} \rightarrow N_{2} O_{\left(g\right)} + 3CO_{2 \left(g\right)}}\)

 ${\mathrm{N}}_2<mspace\; width="1em"></mspace>+<mspace\; width="1em"></mspace>3<mspace\; width="1em"></mspace>{\mathrm{H}}_2<mspace\; width="1em"></mspace>\to <mspace\; width="1em"></mspace>2{\mathrm{NH}}_{3<mspace\; width="1em"></mspace>;}<mspace\; width="1em"></mspace>{∆}_{\mathrm{r}}{\mathrm{H}}^{°}<mspace\; width="1em"></mspace>=<mspace\; width="1em"></mspace>-92.4<mspace\; width="1em"></mspace>\mathrm{kJ}<mspace\; width="1em"></mspace>{\mathrm{mol}}^{-1}$. The standard enthalpy of formation of ${\mathrm{NH}}_3$ gas in the above reaction would be:

The standard enthalpy of the formation of CH₃OH_(l) from the following data is:

${∆}_{\mathrm{vap}}\mathrm{H}°$ $\left({\mathrm{CCl}}_4\right)$ $=$ $30.5$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
${∆}_{\mathrm{f}}\mathrm{H}°$ $\left({\mathrm{CCl}}_4\right)$ $=$ $-$ $135.5$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
${∆}_{\mathrm{a}}\mathrm{H}°$ $\left(\mathrm{C}\right)$ $=$ $715.0$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
${∆}_{\mathrm{a}}\mathrm{H}°$ $\left({\mathrm{Cl}}_2\right)\hspace{0.17em}=$ $242$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$

The enthalpy change for the reaction

 ${\mathrm{CCl}}_4$ $\left(\mathrm{g}\right)$ $\to$ $\mathrm{C}\left(\mathrm{g}\right)$ $+$ $4\mathrm{Cl}$ $\left(\mathrm{g}\right)$ would be:

For an isolated system with ∆U = 0, the ∆S value will be:

For the reaction at 298 K,

2A + B → C

ΔH = 400 kJ mol⁻¹ and ΔS = 0.2 kJ K⁻¹ mol⁻¹. The reaction will become spontaneous at:

The value of ∆G°  for the given reaction would be:
\( 2 \mathrm{~A}(\mathrm{~g})+\mathrm{B}(\mathrm{~g}) \rightarrow 2 \mathrm{D}(\mathrm{~g})\)
(Given: ∆U° = – 10.5 kJ and  ∆S° = – 44.1 J K^–1)

The equilibrium constant for a reaction is 10. The value of $∆\mathrm{G}°$ will be:

($\mathrm{R}$ $=$ $8.314$ $\mathrm{J}$ ${\mathrm{K}}^{-1}$ ${\mathrm{mol}}^{-1}$ $;$ $\mathrm{T}$ $=$ $300$ $\mathrm{K}$)

$1.$ $-5.74$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
$2.$ $-$ $5.74$ $\mathrm{J}$ ${\mathrm{mol}}^{-1}$
$3.$ $+$ $4.57$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
$4.$ $-57.4$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$

The reaction of cyanamide, ${\mathrm{NH}}_2\mathrm{CN}$ $\left(\mathrm{s}\right)$ with dioxygen, was carried out in a bomb calorimeter, and ∆U was found to be $-742.7$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$ at 298 K.
\(\small{\mathrm{NH}_2 \mathrm{CN}(\mathrm{s})+\frac{3}{2} \mathrm{O}_2(\mathrm{g}) \rightarrow \mathrm{N}_2(\mathrm{g})+\mathrm{CO}_2(\mathrm{g})+\mathrm{H}_2 \mathrm{O}(\mathrm{l})}\)

${}_{}$The enthalpy change for the reaction at 298 K would be:

$1.$ $-741.3$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
$2.$ $+$ $753.9$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
$3.$ $+$ $772.$ $7$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$
$4.$ $-845.$ $1$ $\mathrm{kJ}$ ${\mathrm{mol}}^{-1}$