2Zn+O22ZnO    G°=-616 J
2Zn+S22ZnS     G°=-293 J
S2+2O22SO2     G°=-408J

G° for the following reaction is:

2ZnS+3O22ZnO+2SO2

1. -731 J 2. -1317 J
3. -501 J 4. +731 J
Subtopic:  Gibbs Energy Change | Thermochemistry |
 82%
Level 1: 80%+
AIPMT - 2000
Hints

Given that the standard heats of combustion (ΔH°) of C(s), H₂(g), and CH₄(g) are −94 kcal/mol, −68 kcal/mol, and −213 kcal/mol, respectively.
What is the standard enthalpy change (ΔH°) for the reaction:

C(s) + 2H₂(g) → CH₄(g)?

1. – 17 Kcal 2. – 111 Kcal
3. – 170 Kcal 4. – 85 Kcal
Subtopic:  Thermochemistry |
 85%
Level 1: 80%+
AIPMT - 2002
Hints

The formation of a solution from two components can be considered as:

(i) Pure solvent → separated solvent molecules, ∆H1
(ii) Pure solute → separated solute molecules, ∆H2
(iii) Separated solvent and solute molecules → solution, ∆H3


The solution so formed will be ideal if:

1. ∆HSoln = ∆H1 + ∆H2 + ∆H3

2. ∆HSoln = ∆H1 + ∆H2 – ∆H3

3. ∆HSoln = ∆H1 – ∆H2 – ∆H3

4. ∆HSoln = ∆H3 – ∆H1 – ∆H2

Subtopic:  Thermochemistry |
Level 3: 35%-60%
AIPMT - 2003
Hints

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For which one of the following equations is H°reaction equal to H°formation for the product:

1. N2(g) + O3(g) → N2O3(g)

2. CH4(g) + 2Cl2(g) → CH2Cl2(l) + 2HCl(g)

3. Xe(g) + 2F2(g) → XeF4(g)

4. 2CO(g) + O2(g) → 2CO2(g)

Subtopic:  Thermochemistry |
 56%
Level 3: 35%-60%
AIPMT - 2003
Hints

If the bond energies of H–H, Br – Br, and H –Br are 433, 192, and 364 kJ mol–1 respectively, the ∆Hº for the reaction H2(g) + Br2(g) → 2HBr(g) will be:

1. +103 kJ 2. +261kJ
3. –103 kJ 4. –261 kJ
Subtopic:  Thermochemistry |
 76%
Level 2: 60%+
AIPMT - 2004
Hints