The thermodynamic stability of NO(g) based on the given data is:

12N2(g)+12O2(g)NO(g);
rH°=90kJmol-1
NO(g)+12O2(g)NO2(g);
rH°=-74kJmol-1

1. Less than NO2(g) 

2. More than NO2(g)

3. Equal to NO2(g)

4. Insufficient data

Subtopic:  Enthalpy & Internal energy |
 71%
Level 2: 60%+
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The entropy change in the surroundings when 1.00 mol of H2O(l) is formed under standard conditions is:

[Given: ∆fHθ = –286 kJ mol–1 ]

1. 952. 5 J mol-1

2. 979.7 J mol-1

3. 949.7 J mol-1

4. 959.7 J mol-1

Subtopic:  Spontaneity & Entropy |
 54%
Level 3: 35%-60%
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For the graph given below, it can be concluded that work done during the process shown will be-

1. Zero 2. Negative
3. Positive 4. Cannot be determined
Subtopic:  First Law of Thermodynamics |
 68%
Level 2: 60%+
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Consider the following graph.

The work done, as per the graph above, is:

1. Positive 2. Negative
3. Zero 4. Cannot be determined
Subtopic:  First Law of Thermodynamics |
 73%
Level 2: 60%+
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Consider the following diagram for a reaction AC


      

The nature of the reaction is-

1. Exothermic

2. Endothermic

3. Reaction at equilibrium

4. None of the above

Subtopic:  Enthalpy & Internal energy |
 84%
Level 1: 80%+
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What is the nature of the reaction depicted in the given diagram for A→C?

1. Exothermic 2. Endothermic
3. Reaction at equilibrium 4. None of these
Subtopic:  Enthalpy & Internal energy |
 83%
Level 1: 80%+
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An enthalpy diagram for a particular reaction is given below:

Which of the following statements is correct?

1. Reaction is spontaneous
2. Reaction is non-spontaneous
3. The spontaneity of the reaction cannot be determined from the graph provided above.
4. None of the above
Subtopic:  Spontaneity & Entropy |
 54%
Level 3: 35%-60%
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The difference between enthalpy (∆H) and internal energy (∆E) for the given below reaction,
under constant temperature, is:
\(C_{3} H_{8} \left(\right. g \left.\right) + 5 O_{2} \left(\right. g \left.\right) \rightarrow 3 CO_{2} \left(\right. g \left.\right) + 4 H_{2} O \left(\right. l \left.\right)\)

1. + RT 2. – 3RT
3. + 3RT 4. – RT
Subtopic:  Enthalpy & Internal energy |
 85%
Level 1: 80%+
AIPMT - 2003
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For the given reaction 

2H2O2(l)  2H2O(l) + O2(g), the heat of formations of H2O2(l)  and H2O (l) are -188 kJ/mol & -286 KJ/mol respectively. The change in the enthalpy of the reaction will be:

1.  – 196 kJ/mol

2.  + 196 kJ/mol

3.  + 948 kJ/mol

4.  – 948 kJ/mol

Subtopic:  Enthalpy & Internal energy |
 77%
Level 2: 60%+
AIPMT - 2001
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Select the correct option based on statements below:
Assertion (A): Work done in an irreversible isothermal process at constant volume is zero.
Reason (R):  Work is assigned a negative sign during expansion and is assigned a positive sign during compression.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  First Law of Thermodynamics |
 79%
Level 2: 60%+
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