1. Less than NO2(g)
2. More than NO2(g)
3. Equal to NO2(g)
4. Insufficient data
The entropy change in the surroundings when 1.00 mol of H2O(l) is formed under standard conditions is:
[Given: ∆fHθ = –286 kJ mol–1 ]
1. 952. 5 J mol-1
2.
3.
4.
For the graph given below, it can be concluded that work done during the process shown will be-
| 1. | Zero | 2. | Negative |
| 3. | Positive | 4. | Cannot be determined |
Consider the following graph.

The work done, as per the graph above, is:
| 1. | Positive | 2. | Negative |
| 3. | Zero | 4. | Cannot be determined |
Consider the following diagram for a reaction .
The nature of the reaction is-
1. Exothermic
2. Endothermic
3. Reaction at equilibrium
4. None of the above
What is the nature of the reaction depicted in the given diagram for A→C?

| 1. | Exothermic | 2. | Endothermic |
| 3. | Reaction at equilibrium | 4. | None of these |
An enthalpy diagram for a particular reaction is given below:
Which of the following statements is correct?
| 1. | Reaction is spontaneous |
| 2. | Reaction is non-spontaneous |
| 3. | The spontaneity of the reaction cannot be determined from the graph provided above. |
| 4. | None of the above |
The difference between enthalpy (∆H) and internal energy (∆E) for the given below reaction,
under constant temperature, is:
\(C_{3} H_{8} \left(\right. g \left.\right) + 5 O_{2} \left(\right. g \left.\right) \rightarrow 3 CO_{2} \left(\right. g \left.\right) + 4 H_{2} O \left(\right. l \left.\right)\)
| 1. | + RT | 2. | – 3RT |
| 3. | + 3RT | 4. | – RT |
For the given reaction
, the heat of formations of are -188 kJ/mol & -286 KJ/mol respectively. The change in the enthalpy of the reaction will be:
1. – 196 kJ/mol
2. + 196 kJ/mol
3. + 948 kJ/mol
4. – 948 kJ/mol
| Assertion (A): | Work done in an irreversible isothermal process at constant volume is zero. |
| Reason (R): | Work is assigned a negative sign during expansion and is assigned a positive sign during compression. |
| 1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false. |