First three ionisation energies (in kJ/mol) of three representative elements are given below:
Element
P 495.8 4562 6910
Q 737.7 1451 7733
R 577.5 1817 2745
Then incorrect option is :
1. Q: Alkaline earth metal.
2. P: Alkali metal.
3. R: s-block element.
4. All three: P,Q & R belong to the same period.
If the ionization enthalpy and negative electron gain enthalpy of an element are 275 and 86 kcal respectively, then the electronegativity of the element on the Pauling scale is:
1. 2.8
2. 0.0
3. 4.0
4. 2.6
Find the incorrect match among the following electronic configurations and their corresponding period and group numbers.
1. [Ar] 3d⁵ 4s¹ → 4th period, 6th groupand for Mg are 178 Kcal mol–1 and 348 Kcal , respectively. The energy required for the reaction, will be:
1. +170 Kcal
2. +526 Kcal
3. –170 Kcal
4. –526 Kcal
Incorrect statement about characteristics regarding halogens is :
1. Ionization energy decreases with increase in atomic number.
2. Electronegativity decreases with increase in atomic number.
3. Electron affinity decreases with increase in atomic number.
4. Enthalpy of fusion increases with increase in atomic number.
Find the correct order of atomic/ionic sizes among the following:
(a) Al³⁺ < Mg²⁺ < Na⁺ < F⁻
(b) Al³⁺ < Mg²⁺ < Li⁺ < K⁺
(c) Fe⁴⁺ < Fe³⁺ < Fe²⁺ < Fe
(d) Mg > Al > Si > P
1. (a), (b) & (c)
2. (b), (c) & (d)
3. (a), (c)
4. (a), (b), (c) & (d)
The electron gain enthalpies of halogens in kJ mol-1 are given below.
F =-332, Cl =-349, Br =-325, I =-295.
The lesser negative value for F as compared to that of Cl is due to:
| 1. | Strong electron-electron repulsions in the compact 2p-subshell of F |
| 2. | Weak electron-electron repulsions in the bigger 3p-subshell of Cl |
| 3. | Smaller electronegativity value of F than Cl |
| 4. | 1 & 2 both |
The correct order among the following options is:
1. F > N > C > Si > Ga - Non-metallic character
2. F > O> Cl >N - Oxidising property
3. C < Si > P > N - Electron affinity value
4. All of the above
In alkaline earth metals, the properties, among the following, that will increase from Be to Ba are:
(i) Atomic radius
(ii) Ionisation energy
(iii) Nuclear charge
| 1. | (i) and (ii) | 2. | (i) and (iii) |
| 3. | (ii) and (iii) | 4. | (i), (ii), and (iii) |
The process that requires absorption of energy is:
1.
2.
3.
4.