The brown ring test for NO3- is enabled due to the formation of the complex ion with the formula:
1. \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} \)
2. \(\mathrm{Fe}\left[\mathrm{NO}(\mathrm{CN})_5\right]^{2-} \)
3. \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{NO}\right]^{2+} \)
4. \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)(\mathrm{NO})_5\right]^{2+} \)
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Subtopic: Detection of Anions |
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A chloride salt (A) upon reaction with an alkali solution gives gas (B) which in turn gives brown ppt (C) with Nessler’s reagent. A, B, and C are respectively:
1. \(NH_4Cl, NH_3\) and \(HgO\)
2. \(NH_4Cl, NH_3\) and \(Hg(NH_2)Cl\)
3. \(NH_4Cl, NH_3\) and \(HgO.Hg(NH_2)Cl\)
4. \(NH_4Cl, NH_3\) and \(HgO.Hg(NH_2)I\)
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Subtopic: Detection of Cations |
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An inorganic salt in its aqueous solution produced a white ppt with \(NaOH\) which dissolve in excess of \(NaOH.\) . Its aqueous solution produces light yellow ppt with \(AgNO_3\) and sparingly soluble in \(NH_4OH.\) . This salt, probably, is:
Sodium nitroprusside, when added to an alkaline solution of sulphide ions, produces purple colour ion due to formation of:
1. \(Na[Fe(H_2O)_5NOS]2 \)
2. \(Na_2[Fe(H_2O)_5NOS] \)
3. \(Na_3[Fe(CN)_5NOS] \)
4. \(Na_4[Fe(CN)_5NOS] \)
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Subtopic: Detection of Anions |
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