The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol–1. The dissociation constant of acetic acid is :
(\(\mathrm{\Lambda_{H^{+}}^{o} \ = \ 350 \ S \ cm^{2} \ mol^{-1} }\))
(\(\mathrm{\mathrm{\Lambda_{CH_{3}COO^{-}}^{o} \ = \ 50 \ S \ cm^{2} \ mol^{-1} }}\))
1. mol L–1
2. mol L–1
3. mol L–1
4. mol L–1
Molar conductivities at infinite dilution of
NaCl, HCl, and are 126.4, 425.9, and 91.0 S cm2 mol–1 respectively.
for will be:
1. | \(180.5~S~cm^2~mol^{-1}\) | 2. | \(290.8~S~cm^2~mol^{-1}\) |
3. | \(390.5~S~cm^2~mol^{-1}\) | 4. | \(425.5~S~cm^2~mol^{-1}\) |
The variation of molar conductivity with the concentration of an electrolyte (X) in an aqueous solution is shown in the given figure.
The electrolyte X is:
1. | CH3COOH | 2. | KNO3 |
3. | HCl | 4. | NaCl |
A. | Kohlrausch's law of independent migration of ions is applicable for strong electrolytes only. |
B. | At equilibrium state, \(E_{cell}^{o}\) = 0. |
C. | For the spontaneous cell reaction Ecell > 0 and \(\Delta_rG < 0 \). |
1. | Only A | 2. | B and C |
3. | Only C | 4. | A, B and C |