The vapour pressure of a dilute aqueous solution of glucose is 750 mm of Hg at 373 K. The mole fraction of solute in the solution is-
1. 1/10
2. 1/76
3. 1/7.6
4. 1/35
The vapour pressure of a pure liquid solvent A is 0.80 atm. When a non-volatile substance B is added to the solvent, its vapour pressure drops to 0.60 atm.
Mole fraction of the component B in the solution is:
1. | 0.50 | 2. | 0.75 |
3. | 0.40 | 4. | 0.25 |
An aqueous solution of hydrochloric acid -
1. Obeys Raoult's law
2. Shows negative deviations from Raoult's law
3. Shows positive deviations from Raoult's law
4. Obeys Henry's law at all compositions
The relationship between osmotic pressure at 273 K, when 10 gm glucose (P1), 10 gm urea (P2), and 10 gm sucrose (P3) are dissolved in 250 ml of water, is-
1. P1 > P2 > P3
2. P3 > P1 > P2
3. P2 > P1 > P3
4. P2 > P3 > P1
Lowering in vapour pressure is the highest for:
1. 0.2 m urea
2. 0.1 m glucose
3. 0.1 m MgSO4
4. 0.1 m BaCl2
The osmotic pressure of 5 % (mass-volume) solution of cane sugar at 150 °C (mol. mass of sugar = 342 g/mole) is:
1. | 4 atm | 2. | 5.07 atm |
3. | 3.55 atm | 4. | 2.45 atm |
Freezing point of an aqueous solution is -0.166C. Elevation of boiling point of same solution would be-
(Kb = 0.512 K m-1 and Kf = 1.66 K m-1)
1. | 0.18°C | 2. | 0.05°C |
3. | 0.09°C | 4. | 0.23°C |
The equal weight of a solute is dissolved in an equal weight of two solvents A and B to form a very dilute solution. The relative lowering of vapour pressure for solution B has twice the relative lowering of vapour pressure for solution A.
If and are the molecular weights of solvents A and B respectively, then:
1. =
2. = 2
3. = 4
4. = 2
The van’t Hoff factor (i) for a dilute aqueous solution of a strong electrolyte barium hydroxide is:
1. 0
2. 1
3. 2
4. 3