Identify the incorrect statement.
| 1. | The transition metals and their compounds are known for their catalytic activity due to their ability to adopt multiple oxidation states and to form complexes. |
| 2. | Interstitial compounds are those that are formed when small atoms like H, C or N are trapped inside the crystal lattices of metals. |
| 3. | The oxidation states of chromium in CrO42– and Cr2O72– are not the same. |
| 4. | Cr2+(d4) is a stronger reducing agent than Fe2+(d6) in water. |
Urea reacts with water to form A which will decompose to form B. B when passed through \(\left(Cu\right)^{2 +}\) (aq), deep blue colour solution C is formed. What is the formula of C from the following?
| 1. | \(\left[Cu \left(NH_{3}\right)_{4}\right]^{2 +}\) | 2. | \(Cu \left(\right. OH \left.\right)_{2}\) |
| 3. | \(CuCO_{3} . Cu (OH)_{2}\) | 4. | \(CuSO_{4}\) |
Match the following aspects with the respective metal.
| Aspects | Metal | ||
| (a) | The metal which reveals the maximum number of oxidation states | (i) | Scandium |
| (b) | The metal although placed in a 3d block is not considered as a transition element | (ii) | Copper |
| (c) | The metal which does not exhibit variable oxidation states | (iii) | Manganese |
| (d) | The metal which in +1 oxidation state in aqueous solution undergoes disproportionation | (iv) | Zinc |
Select the correct option:
| Options: | (a) | (b) | (c) | (d) |
| 1. | (i) | (iv) | (ii) | (iii) |
| 2. | (iii) | (iv) | (i) | (ii) |
| 3. | (iii) | (i) | (iv) | (ii) |
| 4. | (ii) | (iv) | (i) | (iii) |
Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of:
| 1. | Lanthanoid contraction |
| 2. | Having similar chemical properties |
| 3. | Belonging to the same group |
| 4. | Diagonal relationship |
Match the statements given in List-I with the corresponding element given in List-II:
| List-I (Characteristics) |
List-II (Elements) |
||
| (a) | Element that exhibits +3 oxidation state only. | (i) | Mn |
| (b) | An element that exhibits more number of oxidation states. | (ii) | Zn |
| (c) | Element which is a reducing agent in its +2 oxidation state. | (iii) | Sc |
| (d) | An element that is not considered as a transition element. | (iv) | Cr |
| (a) | (b) | (c) | (d) | |
| 1. | (iii) | (iv) | (i) | (ii) |
| 2. | (iv) | (i) | (ii) | (iii) |
| 3. | (ii) | (iv) | (iii) | (i) |
| 4. | (iii) | (i) | (iv) | (ii) |
Identify the pair of Lanthanoides with one strong oxidant and one strong reductant:
| 1. | Ce(IV), Tb(IV) | 2. | Yb(II), Eu(II) |
| 3. | Eu(IV), Lu(III) | 4. | Ce(IV), Eu(II) |
| 1. | +6 to +5 | 2. | +7 to +4 |
| 3. | +6 to +4 | 4. | +7 to +3 |
A pair among the following have nearly the same atomic radii:
(Numbers in the parenthesis are atomic numbers).