The number of electrons that can be present in the subshells having m_s value of \(-\frac{1}{2}\) for n = 4 are:

The possible values of n, l, and m for the electron present in 3d would be respectively:

1. n = 3, l = 1, m = – 2, – 1, 3, 1, 2

2. n = 3, l = 3, m = – 2, – 1, 0, 1, 2

3. n = 3, l = 2, m = – 2, – 1, 0, 1, 2

4. n = 5, l = 2, m = – 2, – 1, 0, 1, 2

A pair of d-orbitals having electron density along the axes is: 

1. $d_{z^2},$ $d_{xz}$

2. $d_{xz},$ $d_{zy}$

3. $d_{z^2},$ $d_{x^2-y^2}$

4. $d_{xy},$ $d_{x^2-y^2}$