Standard electrode potential of three metals X, Y and Z are -1.2 V, +0.5 V and -3.0 V respectively. The reducing power of these metals will be: 

1.	Y > X > Z	2.	Z > X > Y
3.	X > Y > Z	4.	Y > Z > X

If the  $E_{cell}^{}$ $0$for a given reaction has a negative value, then which of the following gives the correct relationship for the values of $∆G^0$ $$ $and$ $$ $$ $K_{eq}$?

1.  $∆{\mathrm{G}}^0<0;$ ${\mathrm{K}}_{\mathrm{eq}}>1$

2.  $∆{\mathrm{G}}^0<0;$ ${\mathrm{K}}_{\mathrm{eq}}<1$

3.  $∆{\mathrm{G}}^0>0;$ ${\mathrm{K}}_{\mathrm{eq}}<1$

4.  $∆{\mathrm{G}}^0>0;$ ${\mathrm{K}}_{\mathrm{eq}}>1$

Standard electrode potential for Sn⁴⁺/Sn²⁺ couple is +0.15 V and that for Cr³⁺/Cr couple is -0.74. These two couples in their standard state are connected to make a cell. The cell potential will be:

1. +0.89 V

2. +0.18 V

3. +1.83 V

4. +1.199 V

In producing chlorine by electrolysis, 100 kW power at 125 V is being consumed.
How much chlorine per minute is liberated:
(Given -ECE of chlorine is 0.367 X 10-6 kgC^-1)

1.$\mathrm{ 1}.76\times {10}^{-3}$ $kg$

2. $9.67\times {10}^{-3}$ $kg$

3. $17.61\times {10}^{-3}$ $kg$

4. $3.67\times {10}^{-3}$ $kg$

For the reduction of silver ions with copper metal, the standard cell potential was found to be +0.46 V at 25 °C. The value of standard Gibbs energy, ΔG^o will be: 

(F = 96500 C mol^-1)

1. -89.0 kJ

2. -89.0 J

3. -44.5 kJ

4. -98.0 kJ

An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to:

Al₂O₃ is reduced by electrolysis at low potentials and high currents. If 4.0 x 10⁴ A of current is passed through molten Al₂O₃ for 6 hours, the mass of aluminum produced is:
(Assume 100 % current efficiency, the atomic mass of Al = 27 g mol^-1)

The molar conductance of $\frac{\mathrm{M}}{32}$ solution of a weak monobasic acid is 8.0 ohm^-1 cm² and at infinite dilution is 400 ohm^-1 cm². The dissociation constant of this acid is: 

Given:
(i) ${\mathrm{Cu}}^{2+}+2{\mathrm{e}}^{-}\to \mathrm{Cu}$    E^o = 0.337 V 
(ii) ${\mathrm{Cu}}^{2+}+{\mathrm{e}}^{-}\to {\mathrm{Cu}}^{+}$  E^o = 0.153 V 
Electrode potential, E^o for the reaction, 
${\mathrm{Cu}}^{+}+{\mathrm{e}}^{-}\to \mathrm{Cu}$, will be: 

1. 0.52 V

2. 0.90 V

3. 0.30 V

4. 0.38 V