From the colligative properties of a solution, which one is the best method for the determination of molecular weight of proteins & polymers:

1. Osmotic pressure

2. Lowering of vapour pressure 

3. Lowering of freezing point

4. Elevation in boiling point

A solution contains a non-volatile solute of molecular mass M₂. The molecular mass of solute in terms of osmotic pressure is:
where:

m₂ → Mass of solute

V → Volume of solution

\(\pi\) → Osmotic pressure

1. ${\mathrm{M}}_2=\left(\frac{{\mathrm{m}}_2}{\mathrm{\pi }}\right)\mathrm{VRT}$

2. ${\mathrm{M}}_2=\left(\frac{{\mathrm{m}}_2}{\mathrm{V}}\right)\frac{\mathrm{RT}}{\mathrm{\pi }}$

3. ${\mathrm{M}}_2=\left(\frac{{\mathrm{m}}_2}{\mathrm{V}}\right)\mathrm{\pi RT}$

4. ${\mathrm{M}}_2=\left(\frac{{\mathrm{m}}_2}{\mathrm{V}}\right)\frac{\mathrm{\pi }}{\mathrm{RT}}$

The ideal solution indicates:

Beans get cooked earlier in a pressure cooker, because:

Camphor is often used in molecular mass determination because:

1. It has a very high cryoscopic constant

2. It is volatile

3. It is a solvent for organic substances

4. It is readily available 

The vapour pressure of a solvent decreased by 10 mm of Hg when a non-volatile solute was added to the solvent. The mole fraction of the solute in solution is 0.2. What would be the mole fraction of the solvent if the decrease in vapour pressure is 20 mm of Hg:
1. 0.2
2. 0.4
3. 0.6
4  0.8

1 % (w/w) solution of a compound is isotonic with 5 % (w/w) sucrose (sugar) solution. The molecular weight of the compound will be:

The addition of water vapour does not change the density of:

1. CCl₄

2. CS₂

3. Ether

4. Coke

A solution has a 1:4 mole ratio of pentane to hexane.
The vapor pressures of the pure hydrocarbons at 20 ºC are
440 mm Hg for pentane and 120 mm Hg for hexane.
The mole fraction of pentane in the vapor phase would be:

A solution of urea (molar mass 56 g mol^–1) boils at 100.18 ºC at atmospheric pressure. If K_f and K_b for water are 1.86 and 0.512 K kg mol^–1 respectively, the above solution will freeze at:

1. –6.54 ºC

2. –0.654 ºC

3. 6.54 ºC

4. 0.654 ºC