Given below are two statements: 

Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of a disproportionation reaction.
Reason (R): The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in O2
and –2 oxidation state in H2O.

1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Redox Titration & Type of Redox |
 89%
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Using the standard electrode potentials of the redox couples given below, which of the following is the strongest oxidizing agent?

E values: Fe3+/Fe2+=+0.77 V 
I2(s)/I-=+0.54 V
Cu2+/Cu=+0.34 V
Ag+/Ag=0.80 V 

1. Fe3+
2. I2(s)
3. Cu2+
4. Ag+

Subtopic:  Application of Electrode Potential |
 81%
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EΘ values of some redox couples are given below. On the basis of these values choose the correct option.

EΘ values: Br2/Br-=+1.90
Ag+/Ag(s)=+0.80
Cu2+/Cu(s)=+0.34; 
I2(s)/I-=+0.54

1. Cu will reduce Br- 2. Cu will reduce Ag
3. Cu will reduce I- 4. Cu will reduce Br2
Subtopic:  Emf & Electrode Potential |
 58%
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In the reactions given below, thiosulphate reacts differently with iodine than with bromine.

2S2O32-+I2S4O62-+2I-

S2O32-+2Br2+5H2O2SO42-+2Br-+10H+

Choose the statements among the following that best describe the above dual behaviour of thiosulphate.

1. Bromine is a stronger oxidant than iodine
2. Bromine is a weaker oxidant than iodine
3. Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions
4. Bromine undergoes oxidation and iodine undergoes reduction in these reactions

Subtopic:  Oxidizing & Reducing Agents |
 61%
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The incorrect statement regarding the rule to find the oxidation number among the following is-

1. The oxidation number of hydrogen is always +1.
2. The algebraic sum of all the oxidation numbers carried by elements in a compound is zero.
3. An element in its free or uncombined state has an oxidation number of zero.
4. Generally, in all its compounds, the oxidation number of fluorine is -1.

Subtopic:  Oxidizing & Reducing Agents |
 76%
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Which of the following arrangements represents the increasing oxidation number of the central atom?

1. CrO2-, ClO3-, CrO42-, MnO4-

2. ClO3-, CrO42-, MnO4-, CrO2-

3. CrO2-, ClO3-, MnO4-, CrO42-

4. CrO42-, MnO4-, CrO2-, ClO3-

Subtopic:  Oxidizing & Reducing Agents |
 88%
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The largest oxidation number exhibited by an element depends on its electronic configuration. With which of the following electronic configurations will the element exhibit the largest oxidation number?

1. 3d14s2

2. 3d34s2

3. 3d54s1

4. 3d54s2

Subtopic:  Oxidizing & Reducing Agents |
 73%
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Identify the disproportionation reaction among the following:

1. CH4+2O2  → CO2+2H2O

2. CH4+4Cl→ CCl4+4HCl

3. 2F2+2OH→ 2F-+OF2+H2O

4. 2NO2+2OH→ NO2-+NO3-+H2O

Subtopic:  Redox Titration & Type of Redox |
 60%
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Given below are two statements: 

Assertion (A): Among halogens, fluorine is the best oxidant.
Reason (R): Fluorine is the most electronegative atom.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Emf & Electrode Potential |
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Given below are two statements: 

Assertion (A): In the reaction between potassium permanganate and potassium iodide, permanganate ions act as an oxidising agent.
Reason (R): The oxidation state of manganese changes from +2 to +7 during the reaction.

1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. (A) is false but (R) is true.

Subtopic:  Redox Titration & Type of Redox |
 64%
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