The Mn3+ ion is unstable in solution and undergoes disproportionation reaction to give Mn2+, MnO2 and H+ ion. The balanced ionic equation for the reaction is-

1. \(\small{2 \mathrm{Mn}^{3+}{ }_{(\mathrm{aq})}+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow \mathrm{MnO}_{2(\mathrm{~s})}+\mathrm{Mn}^{2+}{ }_{(\mathrm{aq})}+4 \mathrm{H}^{+}{ }_{(\mathrm{aq})}}\)
2. Mn3+(aq) + H2O(l) → MnO2(s) + 2Mn2+(aq) + 4H+(aq)
3. \(\small{5 \mathrm{Mn}^{3+}(\mathrm{aq})+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow \mathrm{MnO}_{2(\mathrm{s})}+3 \mathrm{Mn}^{2+}(\mathrm{aq})+4 \mathrm{H}^{+}(\mathrm{aq})}\)
4. \(\small{2 \mathrm{Mn}^{3+}{ }_{(\mathrm{aq})}+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow 2 \mathrm{MnO}_{2(\mathrm{s})}+2 \mathrm{Mn}^{2+}{ }_{(\mathrm{aq})}+4 \mathrm{H}^{+}{ }_{(\mathrm{aq})}}\)

Subtopic:  Emf & Electrode Potential |
 79%
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Which element exhibits both positive and negative oxidation states?

1. Cs 2. Ne
3. I 4. F
Subtopic:  Introduction to Redox and Oxidation Number |
 64%
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The balanced equation for the reaction between chlorine and sulphur dioxide in water is-

1. Cl2(s) + SO2(aq) + 2H2O(I) →2Cl-(aq) + SO42-(aq) + 4H+(aq)
2. 3Cl2(s) + SO2(aq) + 2H2O(I) →Cl-(aq) + SO42-(aq) + 3H+(aq)
3. Cl2(s) + 3SO2(aq) + H2O(I) →Cl-(aq) + 2SO42-(aq) + 4H+(aq)
4. 2Cl2(s) + SO2(aq) + H2O(I) →2Cl-(aq) + SO42-(aq) + 4H+(aq)

Subtopic:  Balancing of Equations |
 83%
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The set of metals that can show disproportionation reaction is -

1. Cu, Na, Li 2. Mg, F, Ne
3. P, Cl, S 4. Mn, Cu, Ga
Subtopic:  Redox Titration & Type of Redox |
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The maximum weight of nitric oxide that can be obtained starting only with 10.00 g of ammonia and 20.00 g of oxygen is -

1. 9 g 2. 15 g
3. 12 g 4. 11g
Subtopic:  Balancing of Equations |
 64%
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Consider the given data:

EFe3+/Fe2+=0.77; EI-/I2= -0.54
EAg+/Ag=0.80; ECu/Cu2+= -0.34
EFe3+/Fe2+=0.77; ECu/Cu2+= -0.34
EAg/Ag+=-0.80; EFe3+/Fe2+=0.77

Using the electrode potential values given above, identify the reaction which is not feasible:

1. Fe3+(aq) and I- aq)
2. Ag+(aq) and Cu(s)
3. Fe3+(aq) and Cu(s)
4. Ag(s) and Fe3+(aq)

Subtopic:  Application of Electrode Potential |
 61%
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The correct statement about the electrolysis of an aqueous solution of AgNO3 with Ag electrode is-

1. Ag+ ion gets oxidised at cathode; Ag(s) is reduced at anode
2. H2O gets reduced at cathode; H2O gets oxidised at anode
3. Ag+ ion gets reduced at cathode; H2O is oxidised at anode
4. Ag+ ion gets reduced at cathode; Ag(s) is oxidised at anode

Subtopic:  Application of Electrode Potential |
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The correct statement about the electrolysis of an aqueous solution of AgNO3 with Pt electrode is:
 

1. Pt(s) gets oxidized at cathode whereas  Ag + ( aq )  gets reduced at anode
2. Ag+ (aq)  gets reduced at cathode and is oxidized at anode
3. Ag+ (aq) gets reduced at cathode whereas water is oxidized at anode
4. Ag (s) gets oxidized at cathode whereas  H2O  is oxidised at anode

Subtopic:  Emf & Electrode Potential |
 60%
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The correct statement about electrolysis of an aqueous solution of CuCl2 with Pt electrode is-

1. Cu2+  ion reduced at the cathode;  Cl-  ion oxidized at the anode 
2. Cu2+  ion reduced at the anode;  Cl-  ion oxidized at the cathode
3. Cu2+  ion reduced at the cathode;  H2O  ion oxidized at the anode 
4. H2O  ion reduced at the cathode;  Cl-  ion oxidized at the anode 

Subtopic:  Emf & Electrode Potential |
 66%
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The oxidizing agent and reducing agent in the given reaction are :

3N2H4l+4ClO3aq-
6NOg+4Claq-+6H2Ol

1. Oxidising agent = N2H4; Reducing agent = ClO3-

2. Oxidising agent = ClO3-; Reducing agent = N2H4

3. Oxidising agent = N2H4 ; Reducing agent = N2H4

4. Oxidising agent = ClO3- ; Reducing agent = ClO3-

Subtopic:  Oxidizing & Reducing Agents |
 82%
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