pH of a saturated solution of is 9. The solubility product of is:
1.
2.
3.
4.
The conjugate bases of Bronsted acids H2O and HF are respectively:
1. H3O+ and H2F+, respectively.
2. OH- and H2F+, respectively.
3. H3O+ and F-, respectively.
4. OH- and F-, respectively.
Which will make basic buffer:
1. | 100 mL of 0.1 M HCl+100 mL of 0.1 M NaOH |
2. | 50 mL of 0.1 M NaOH+25 mL of 0.1 M CH3COOH |
3. | 100 mL of 0.1 M CH3COOH+100 mL of 0.1 M NaOH |
4. | 100 mL of 0.1 M HCl+200 mL of 0.1 M NH4OH |
The hydrogen ion concentration of a 10-8 M HCl aqueous solution at 298 K (Kw = 10-14) is:
1.
2.
3.
4.
The following pair constitutes a buffer is:
1.
2.
3.
4.
For the reaction,
CH4(g) + 2O2(g) CO2(g) + 2H2O(l)
ΔrH = -170.8 kJ mol-1
Which of the following statements is not true?
1. | At equilibrium, the concentration of \(\mathrm{CO}_2 \mathrm{~g}\) and water (l) are not equal. |
2. | The equilibrium constant for the reaction is given by \(K_p=\frac{\left[\mathrm{CO}_2\right]}{\left[\mathrm{CH}_4\right]\left[\mathrm{O}_2\right]}\) |
3. | The addition of \(\mathrm{CH}_4 \mathrm{~g} \) or \(\mathrm{O}_2 \mathrm{~g}\) at equilibrium will cause a shift to the right |
4. | The reaction is exothermic |
Which one of the following orders correctly represents the increasing acid strengths of the given acids?
1.
2.
3.
4.
The ionic species that has the greatest proton affinity to form stable compound is:
1.
2.
3.
4.
The following equilibrium constants are given:
N2 + 3H2 ⇌ 2NH3; K1
N2 + O2 ⇌ 2NO; K2
H2 + 1/2O2 ⇌ H2O; K3
The equilibrium constant for the oxidation of NH3 by oxygen to give NO is:
1.
2.
3.
4.
A weak acid, HA, has a Ka of 1.00×10-5. If 0.100 mole of this acid is dissolved in one litre of water, the percentage of acid dissociated at equilibrium is closest to:
1. 99.0%
2. 1%
3. 99.9%
4. 0.100%