When the initial concentration of ICl is 0.78 M, the equilibrium concentration of ICl will be: 

2ICl(g) ⇋ I2(g) + Cl2(g); Kc = 0.14

1. 0.446 M 2. 0.876 M
3. 0.345 M 4. 0.986 M

Subtopic:  Kp, Kc & Factors Affecting them |
 52%
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Given the reaction:
CH
3COOH(l) + C2H5OH(l)  CH3COOC2H5(l) + H2O(l)

At 293 K, if one starts with 1.00 mol of acetic acid and 0.18 mol of ethanol, there is 0.171 mol of ethyl acetate in the final equilibrium mixture. The equilibrium constant of the reaction will be-

1. 0.78

2. 1.3

3. 2.47

4. 3.92

Subtopic:  Kp, Kc & Factors Affecting them |
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(a) PCl5 (g) PCl3 (g) + Cl2 (g)

(b) CaO (s) + CO2 (g)   CaCO3 (s)

(c) 3Fe (s) + 4H2O (g)  Fe3O4 (s) + 4H2 (g)

The effect of an increase in the volume on the number of moles of products in the above-mentioned reactions would be, respectively:

1. a) Increase,  b) decrease, c) same

2. a) Decrease,  b) same, c) increase

3. a) Increase,  b) increase, c) same

4. a) Increase,  b) decrease, c) increase

Subtopic:  Le Chatelier's principle |
 70%
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Consider the following reactions.

(i) COCl2 (g)  ⇋ CO (g) + Cl2 (g)

(ii) CO2 (g) + C (s)  2CO (g)

(iii) 2H2 (g) + CO (g)  CH3OH (g)

Which reaction(s) will shift in a backward manner when the pressure is increased?

1. Only (iii)

2. Only (ii)

3. Both (i) and (ii) 

4. None of the above

Subtopic:  Le Chatelier's principle |
 72%
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Given an endothermic reaction:

CH4 (g) + H2O (g)  ⇋ CO (g) + 3H2 (g)

If the temperature is increased, then 

1. The equilibrium will not be disturbed.

2. The equilibrium will shift in the backward direction.

3. The equilibrium will shift in the forward direction.

4. None of the above

Subtopic:  Le Chatelier's principle |
 80%
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For the given reaction: 

PCl5 (g)  PCl3 (g) + Cl2 (g), ∆r = 124.0 kJ mol–1 and Kc = 8.3 × 10-3 mol L-1 at 473 K

The effect on Kc if (i) pressure is increased  and (ii) the temperature is increased will be, respectively-

1. (i) Will increase; (ii) will decrease

2. (i) Will decrease; (ii) will remain the same 

3. (i) Will remain the same; (ii) will increase

4. (i) will remain the same; (ii) Will decrease

Subtopic:  Kp, Kc & Factors Affecting them |
 75%
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The conjugate acid-base pair is 

1. A pair that differs only by one proton

2. A pair that differs only by the size

3. A pair that differs only by electronegativity

4. None of the above

Subtopic:  Acids & Bases - Definitions & Classification |
 91%
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The conjugate bases for Brönsted acids, H2SO4, and HCO3- will be, respectively:

1. HSO4-CO32-

2.  HSO4-, CO3-

3. SO4-2, CO32-

4. HS2O4-, CO32-

Subtopic:  Acids & Bases - Definitions & Classification |
 85%
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The conjugate acids for the Brönsted bases  NH2- , NH3 and HCOOwill be respectively:

1. N2H6, NH4+, HCOOH

2. NH3, NH4+ , HCOOH

3. NH3, NH4+, HCOO3

4. N2H, NH4+, HCOOH

Subtopic:  Acids & Bases - Definitions & Classification |
 93%
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 OH , F , H+ and BCl3 

The species described above that contain Lewis acids are:

1. BCl3 and F-

2. OH– and F-

3. H+and BCl3

4. F- and BCl3

Subtopic:  Acids & Bases - Definitions & Classification |
 78%
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