The pH of neutral water at $25°\mathrm{C}$ is 7.0. As the temperature increases, ionisation of water increases. However, the concentration of H⁺ ions and OH^- ions is equal. The pH of pure water at $60°\mathrm{C}$ is:

1.	Equal to 7.0	2.	Greater than 7.0
3.	Less than 7.0	4.	Equal to zero

The ionisation constant of an acid, K_a , is the measure of the strength of an acid. The K_a values of acetic acid, hypochlorous acid and formic acid are $1.74\times {10}^{-5}, 3.0\times {10}^{-8}$ and $1.8\times {10}^{-4}$ , respectively. The  correct order of pH value of 0.1 mol dm^-3 solutions of these acids is -

1. Acetic acid > hypochlorous acid > formic acid

2. Hypochlorous acid < acetic acid > formic acid

3. Formic acid > hypochlorous acid > acetic acid

4. Formic acid < acetic acid < hypochlorous acid

${\mathrm{K}}_{{\mathrm{a}}_1},$ ${\mathrm{K}}_{{\mathrm{a}}_2}$ $\mathrm{and}$ ${\mathrm{K}}_{{\mathrm{a}}_3}$ are the respective ionisation constants for the following reactions.
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons \mathrm{H}^{+}+\mathrm{HS}^{-}\)
\(\mathrm{HS}^{-} \rightleftharpoons \mathrm{H}^{+}+\mathrm{S}^{2-}\)
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{S}^{2-}\)
The correct relationship between ${\mathrm{K}}_{{\mathrm{a}}_1},$ ${\mathrm{K}}_{{\mathrm{a}}_2}$ $\mathrm{and}$ ${\mathrm{K}}_{{\mathrm{a}}_3}$ is:

Acidity of BF₃ can be explained on the basis of: 

1. Arrhenius concept

2. Bronsted Lowry concept 

3. Lewis concept

4. Bronsted Lowry as well as Lewis concept

The mixture that will produce a buffer solution when mixed in equal volumes is:

Among the following solvents, silver chloride is most soluble in:

1. $0.1 \mathrm{mol} {\mathrm{dm}}^{-3} {\mathrm{AgNO}}_3$ solution

2. $0.1 \mathrm{mol} {\mathrm{dm}}^{-3} \mathrm{HCl}$ solution

3. ${\mathrm{H}}_2\mathrm{O}$

4. Aqueous ammonia

The value of the pH of \(0.01 \) \(\text{mol dm}^{-3}   \)\(\text{CH}_3\text{COOH}\) \(\left(K_a=1.74 \times 10^{-5}\right)\)  is:

Which of the following alternatives best describes the reaction A ⇌ B at its halfway point?

On increasing the pressure, the direction in which the gas phase reaction proceeds to re-establish equilibrium is predicted by applying Le-Chatelier's principle. Consider the reaction,

${\mathrm{N}}_2\left(\mathrm{g}\right)+3{\mathrm{H}}_2\left(\mathrm{g}\right)\rightleftharpoons 2{\mathrm{NH}}_3\left(\mathrm{g}\right)$

Which of the following is correct, if the total pressure at which the equilibrium is established is increased without changing the temperature?

The addition of a small amount of argon at a constant volume will not affect the equilibrium of the following reaction: