For the following equilibrium, Kc= 6.3 × 1014 at 1000 K

NO(g) + O3 (g)  NO2(g) + O2 (g) 

The value of Kc for the reverse reaction is:

1. 2.33 × 10-16
2. 1.59 × 10-15
3. 2.67 × 10-13
4. 4.47 × 1014

Subtopic:  Kp, Kc & Factors Affecting them |
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\(\mathrm{K}_{\mathrm{c}}=\frac{\left[\mathrm{NH}_3\right]^4\left[\mathrm{O}_2\right]^5}{[\mathrm{NO}]^4\left[\mathrm{H}_2 \mathrm{O}]^6\right.}\)
The balanced chemical equation corresponding to the above-mentioned expression is:

1. \(4 \mathrm{NO}_{(\mathrm{g})}+6 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons 4 \mathrm{NH}_{3(\mathrm{g})}+5 \mathrm{O}_{2(\mathrm{g})} \)
2. \(4 \mathrm{NH}_3(\mathrm{g})+5 \mathrm{O}_{2(\mathrm{g})} \rightleftharpoons 4 \mathrm{NO}_{(\mathrm{g})}+6 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\)
3. \(\ 2 \mathrm{NO}_{(\mathrm{g})}+3 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons 4 \mathrm{NH}_{3(\mathrm{g})}+3 \mathrm{O}_{2(\mathrm{g})}\)
4. \(\ \mathrm{NH}_{3(\mathrm{g})}+3 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons 2 \mathrm{NO}_{(\mathrm{g})}+3 \mathrm{O}_{2(\mathrm{g})}\)
Subtopic:  Kp, Kc & Factors Affecting them |
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One mole of H2O and one mole of CO are taken in a 10 L vessel and heated to
725
 K. At equilibrium, 40% of water(by mass) reacts with CO according to the equation,

H2O (g) + CO (g)  H2 (g) + CO2 (g)

The equilibrium constant for the above-mentioned reaction would be:

1. 0.66 2. 0.35
3. 0.44 4. 0.82


 

Subtopic:  Kp, Kc & Factors Affecting them |
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The equilibrium pressure of C2Hwhen it is placed in a flask at 4.0 atm pressure at  899 K would be:

C2H6 (g)   C2H4 (g) + H2 (g)

Kp = 0.04 atm at 899 K)

1. 4.12 atm 2. 3.62 atm
3. 1.54 atm 4. 2.16 atm
Subtopic:  Kp, Kc & Factors Affecting them |
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A sample of pure PCl5 was introduced into an evacuated vessel at 473 K.
After equilibrium was attained, a concentration of PCl
5 
was found to be 0.5 × 10
–1 mol L–1. If the value of
 
Kc is 8.3 × 10–3 mol L–1, the concentrations of
PCl
3 and Cl2 at equilibrium would be:

PCl5 (g)  ⇋ PCl3 (g) + Cl2(g)
 

1.  [PCl3] = 0.02 mol L-1 ,  [Cl2] = 0.04 mol L-1
2. [PCl3]=[Cl2] = 0.02 mol L-1
3. [PCl3] = 0.04 mol  L-1, [Cl2] =0.02 mol L-1
4. [PCl3]= [Cl2] = 0.04 mol L-1

Subtopic:  Kp, Kc & Factors Affecting them |
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Match the following equilibria with the corresponding condition.

A. LiquidVapour 1. Saturated solution
B. SolidLiquid 2. Boiling point
C. SolidVapour 3. Sublimation point
D. Solute (s)Solute (solution) 4. Melting point
5. Unsaturated solution

Codes

A B C D
1. 2 4 3 1
2. 1 2 3 5
3. 5 4 3 2
4. 4 5 3 2
Subtopic:  Introduction To Equilibrium |
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Some reactions are written below in Column I and their equilibrium constants
in terms of Kc are written in Column II.
Match the following reactions with the corresponding equilibrium constant.

Column I (Reaction) Column II (Equilibrium constant)
A. 2N2(g)+6H2(g)4NH3(g) 1. 2Kc
B. 2NH3(g)N2(g)+3H2(g) 2. Kc1/2
C. 12N2(g)+32H2(g)NH3(g) 3. 1Kc
4. Kc2

Codes

A B C
1. 4 3 2
2. 1 2 3
3. 1 4 3
4. 4 1 3
Subtopic:  Kp, Kc & Factors Affecting them |
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Match the standard free energy of the reaction with the corresponding equilibrium constant.

A. G>0 1. K>1
B. G<0 2. K=1
C. G=0 3. K=0
4. K<1

Codes

A B C
1. 4 1 2
2. 1 2 3
3. 2 4 3
4. 4 1 3
Subtopic:  Kp, Kc & Factors Affecting them |
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Match the following species with the corresponding conjugate acid.

Species Conjugate acid
A.  NH3  1. CO32-
B. HCO3- 2. NH4+
C. H2O 3.H3O+
D. HSO4-  4. H2CO3
5. H2SO4

Codes

A B C D
1. 2 5 1 5
2. 2 4 3 5
3. 5 4 3 2
4. 4 5 3 2
Subtopic:  Acids & Bases - Definitions & Classification |
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A

B

A. 

i. Variation in product concentration with time.

B. 

ii. Reaction at equilibrium

C. 

iii. Variation in reactant concentration with time.

Match the graphical variations with their descriptions given above and identify the correct codes below:

A B C
1. i iii ii
2. i ii iii
3. iii ii i
4. iii i ii
Subtopic:  Kp, Kc & Factors Affecting them |
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