Which of the following is an example of a reversible reaction?
1. \(\small{KNO_3(aq) + NaCl(aq) \rightleftharpoons KCl(aq) + NaNO_3(aq)}\)
2. \(\small{2Na(s) + H_2O(l) \rightleftharpoons 2NaOH(aq) + H_2(g)}\)
3. \(\small{AgNO_3(aq) + NaCl(aq) \rightleftharpoons AgCl(s) + NaNO_3(aq)}\)
4. \(\small{Pb{(NO_3)}_2(aq) + 2NaI(aq) \rightleftharpoons PbI_2(s) + 2NaNO_3(aq)}\)

If a solution of 0.1 M NH₄OH and 0.1 M NH₄Cl has pH 9.25, then the pK_b of NH₄OH will be:

At 25°C, the pH of a solution containing 0.10 M sodium acetate and 0.03 M acetic acid will be:

[pK_a value of ${\mathrm{CH}}_3\mathrm{COOH}=4.57$]-

1. 3.24

2. 4.59

3. 5.09

4. 6.67

The ratio of the concentration of salt and acid for preparing a buffer solution of pH 6 by mixing sodium acetate and acetic acid will be: (K_a=10^-5)

1. 1:10

2. 10:1

3. 100:1

4. 1:100

The pH of a solution made by mixing 50 mL of 0.01 M barium hydroxide solution with 50 mL of H₂O is

The solution with pH value close to 1.0 among the following is:

The pH of a 0.05 M aqueous solution of diethylamine is 12. Its K_b value will be:

1. $2\times {10}^{-3}$

2. $2.5\times {10}^{-3}$

3. $3\times {10}^{-3}$

4. $4.5\times {10}^{-3}$

K_a for HCN is $5\times {10}^{-10}$ at $25°\mathrm{C}$. For maintaining a constant pH of 9, the volume of 5 M KCN solution required to be added to 10 mL of 2 M HCN solution is-

1. 2 mL

2. 3 mL

3. 4.2 mL

4. 5.6 mL

Which of the following compounds is in the correct sequence in terms of relative basic strength?

1. ${\mathrm{C}}_2{\mathrm{H}}_5{\mathrm{O}}^{-}>\mathrm{CH}\equiv {\mathrm{C}}^{-}>{\mathrm{OH}}^{-}$

2. $\mathrm{CH}\equiv {\mathrm{C}}^{-}{>}^{-}\mathrm{OH}>{\mathrm{C}}_2{\mathrm{H}}_5{\mathrm{O}}^{-}$

3. $\mathrm{CH}\equiv {\mathrm{C}}^{-}>{\mathrm{C}}_2{\mathrm{H}}_5{\mathrm{O}}^{-}>{\mathrm{OH}}^{-}$

4. ${\mathrm{C}}_2{\mathrm{H}}_5{\mathrm{O}}^{-}>{\mathrm{OH}}^{-}>\mathrm{CH}\equiv {\mathrm{C}}^{-}$

The concentration of CH₃COOH that will have the same [H⁺] as obtained from 10^-2 M HCOOH, is-

$\left(\mathrm{Ka}\right({\mathrm{CH}}_3\mathrm{COOH})={10}^{-5},$ $\mathrm{Ka}\left(\mathrm{HCOOH}\right)={10}^{-4})$

1. 10 M

2. 5 M

3. 10^-1 M

4. 6 M