Considering H2O as a weak field ligand, the number of unpaired electrons in \([Mn(H_{2}O)_{6}]^{2+}\) will be:
(At. no. of Mn = 25)

1. Five 2. Two
3. Four 4. Three

Subtopic:  VBT, CFT & their Limitations |
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Among [Ni(CO)4], [Ni(CN)4]2−, [ NiCl4]2− species, the hybridization states of the Ni atom are respectively:
(At. No. of Ni = 28)

1. sp3, dsp2, sp3 2. sp3, sp3, dsp2
3. dsp2, sp3, sp3 4. sp3, dsp2 , dsp2
Subtopic:  VBT, CFT & their Limitations |
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Coordination compound that would exhibit optical isomerism is:

1. Diamminedichloroplatinum(II)
2. Trans-dicyanobis(ethylenediamine)chromium(III) chloride
3. Tris-(ethylenediamine)cobalt(III) chloride
4. Pentaamminenitrocobalt(III) iodide
Subtopic:  Isomerism in Coordination Compounds |
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The atomic numbers of Cr and Fe are respectively 24 and 26. Among the following, the one that is paramagnetic with the spin of the electron is:

1. CrCO6

2. FeCO5

3. [Fe(CN)6]4-

4. [Cr(NH3)6]3+

Subtopic:  VBT, CFT & their Limitations |
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The hypothetical complex
chlorodiaquatriamminecobalt(III) chloride can be
represented as:

1. CoClNH33H2O2Cl2

2. CoNH33H2OCl3

3. CoNH23H2O2Cl

4. CoNH33H2O3Cl3

Subtopic:  Introduction, Classification and Nomenclature |
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The coordination compound that gives the maximum number of isomers is:

1. [Co(NH3)4Cl2]

2. [Ni(en)(NH3)4]2+

3. [Ni(C2O4)(en)2]

4. [Cr(SCN)2(NH3)4]+

Subtopic:  Isomerism in Coordination Compounds |
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According to IUPAC nomenclature, sodium nitroprusside is named as:

1. Sodium nitro ferricyanide

2. Sodium nitro ferrocyanide

3. Sodium pentacyanidonitrosyl ferrate(II)

4. Sodium pentacyanonitrosyl ferrate(III)

Subtopic:  Introduction, Classification and Nomenclature |
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The number of unpaired electrons in the complex ion [CoF6]3– is:

(Atomic No. Co = 27)

1. 2

2. 3

3. 4

4. Zero

Subtopic:  VBT, CFT & their Limitations |
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The octahedral complex that will not show geometrical isomerism is: 
 (A and B are monodentate ligands)

1. [MA2B4] 2. [MA3B3]
3. [MA4B2] 4. [MA5B]
Subtopic:  Isomerism in Coordination Compounds |
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A metal ion present in vitamin B12 is:

1. Fe(II) 2. Co(III)
3. Zn(II) 4. Ca(II)
Subtopic:  Organometallic Complexes & their Uses |
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