The complex that can exhibit linkage isomerism is:

1. [Co(NH3)5H2O]Cl3 2. [Co(NH3)5(NO2)]Cl2
3. [Co(NH3)5NO3](NO3)2 4. [CO(NH3)5Cl]SO4

Subtopic:  Isomerism in Coordination Compounds |
 87%
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If an excess of AgNO3 solution is added to 100 mL of a 0.024 M solution of dichlorobis (ethylenediamine) cobalt (III) chloride, then the number of moles of AgCl that will be precipitated is:

1. 0.0012 2. 0.0016
3. 0.0024 4. 0.0048
Subtopic:  Werner’s Theory |
 78%
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Given the following pair of isomers:
[Cr(NH3)6][Cr(NO2)6] and
[Cr(NH3)4(NO2)2][Cr(NH3)2(NO2)4]
Aside from X-ray diffraction, how could the following pairs of isomers be distinguished from one another?

1. Cryoscopic method
2. Measuring their molar conductance
3. Measuring their magnetic moments
4. Observing their colors

Subtopic:  Introduction, Classification and Nomenclature |
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For a tetrahedral complex [MCl4]2-, the spin-only magnetic moment is 3.83 B.M. The element M is:

1. Co

2. Cu

3. Mn

4. Fe

Subtopic:  VBT, CFT & their Limitations |
 80%
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The geometry and magnetic properties of [NiCl4]2-, respectively, are : 

1. Tetrahedral, Paramagnetic

2. Tetrahedral, Diamagnetic

3. Square planar, Paramagnetic

4. Square planar, Diamagnetic  

Subtopic:  VBT, CFT & their Limitations |
 79%
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The IUPAC name of CoONONH35Cl2 is:

1. Pentamminenitro-O-cobalt(II)chloride

2. Pentamminenitroso-O-cobalt(III)chloride  

3. Pentaamminenitrito-O-cobalt(III) chloride

4. Pentammineoxo-nitrocobalt(III)chloride

Subtopic:  Introduction, Classification and Nomenclature |
 65%
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Which of the following statements about ammonium cerium (IV) nitrate, NH42CeNO36 is incorrect?

1. NO3- acts as a monodentate ligand.
2. The Ce atom has a coordination number of 12.
3. The shape of the complex ion is an icosahedron.
4. The solution is used as an oxidizing agent.

Subtopic:  Ligands |
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The total number of geometrical isomers possible for an octahedral complex of MA2B2C2 are:
(M = transition metal; A, B and C are monodentate ligands)

1. 3 2. 4
3. 5 4. 6
Subtopic:  Isomerism in Coordination Compounds |
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2.335 g of compound X (empirical formal CoH12N4Cl3) upon treatment with excess AgNO3 solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:

[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]

1. 3, 6 2. 3, 4
3. 2, 4 4. 4, 3
Subtopic:  Introduction, Classification and Nomenclature |
 60%
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The geometry and the number of the unpaired electron(s) of \([MnBr_{4}]^{2-}\), respectively, are:

1. Tetrahedral and 1 2. Square planar and 1
3. Tetrahedral and 5 4. Square planar and 5 
Subtopic:  Isomerism in Coordination Compounds |
 77%
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