The crystal field stabilization energy (CFSE) for [CoCl6]4- is 18000 cm-1.
The CFSE for [CoCl4]2-  will be:

1. 6000 cm-1

2. 16000 cm-1

3. 18000 cm-1

4. 8000 cm-1

Subtopic:  VBT, CFT & their Limitations |
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Zero magnetic moment of the octahedral complex K2NiF6 is due to: 

1. Low spin d6 Ni(IV) complex

2. Low spin d8 Ni(ll) complex

3. High spin d8 Ni(ll) complex

4. High spin d6 Ni(IV) complex

Subtopic:  VBT, CFT & their Limitations |
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According to Crystal Field Theory (CFT), the compound, among the following, that forms a colored complex is:

1. [Ti(H2O)6]4+
2. [Cr(NH3)6]3+
3. K[V(F)6]
4. (NH4)2[TiCl6]

Subtopic:  VBT, CFT & their Limitations |
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The hybridizations of [Ni(CO)4] and [Cr(H2O)6]3+, respectively, are : 

1. sp3 and d3sp2

2. dsp2 and d2sp3

3. sp3 and d2sp3

4. dsp2  and sp3d2

Subtopic:  VBT, CFT & their Limitations |
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A metal ion has d6 configuration. In octahedral complex entity of low spin, the number of electrons present in eg set of orbitals will be

1. 6 2. 4
3. 0 4. 2
Subtopic:  VBT, CFT & their Limitations |
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Spin-only magnetic moments of [Fe(NH3)6]3+ and [FeF6]3-  in BM are, respectively :

1. 1.73 and 1.73 2. 5.92 and 1.73
3. 1.73 and 5.92 4. 5.92 and 5.92
Subtopic:  VBT, CFT & their Limitations |
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The number of geometrical isomers of [CrCl2en(NH3)2] are:
[en-ethylenediamine]

1. 2 2. 3
3. 4 4. 1
Subtopic:  Isomerism in Coordination Compounds |
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The geometry and the number of the unpaired electron(s) of \([MnBr_{4}]^{2-}\), respectively, are:

1. Tetrahedral and 1 2. Square planar and 1
3. Tetrahedral and 5 4. Square planar and 5 
Subtopic:  Isomerism in Coordination Compounds |
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2.335 g of compound X (empirical formal CoH12N4Cl3) upon treatment with excess AgNO3 solution produces 1.435 g of a white precipitate. The primary and secondary valences of cobalt in compound X, respectively are:

[Given Atomic mass: Co = 59, Cl = 35.5, Ag = 108]

1. 3, 6 2. 3, 4
3. 2, 4 4. 4, 3
Subtopic:  Introduction, Classification and Nomenclature |
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The total number of geometrical isomers possible for an octahedral complex of MA2B2C2 are:
(M = transition metal; A, B and C are monodentate ligands)

1. 3 2. 4
3. 5 4. 6
Subtopic:  Isomerism in Coordination Compounds |
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