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Q. No.Match the items in column I with the items in column II.
Column I
Column II
a. Hexagonal unit cells
i. a ≠ b ≠ c and α=γ=90°β≠90°
b. Face-centred unit cells
ii. 2 atoms per unit cells
c. Monoclinic unit cells
iii. 4 atoms per unit cell
d. End-centred unit cells
iv. a = b ≠ c and α = β = 90° γ = 120°
1. a-iv; b-ii; c-i, d-iii
2. a-ii; b-i; c-iv, d-iii
3. a-iv; b-iii; c-i, d-ii
4. a-iii; b-iv; c-i, d-ii
1. a-iv; b-ii; c-i, d-iii
2. a-ii; b-i; c-iv, d-iii
3. a-iv; b-iii; c-i, d-ii
4. a-iii; b-iv; c-i, d-ii
Subtopic: Introduction & Crystal System |
84%
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The contribution (per unit cell) of an atom located at (i) corner and (ii) body-centre of a cubic unit cell respectively is :
1. 8 , 1
2. 1/8 , 1
3. 1/2 , 1/4
4. 1/4 , 1
1. 8 , 1
2. 1/8 , 1
3. 1/2 , 1/4
4. 1/4 , 1
Subtopic: Introduction & Crystal System |
89%
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The two dimensional coordination number of a molecule in square close packed layer is-
1. 4
2. 6
3. 5
4. 2
1. 4
2. 6
3. 5
4. 2
Subtopic: Introduction & Crystal System |
75%
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The total number of tetrahedral voids in 0.5 mol compound in hexagonal close-packed structure is-
1. 4.022 ×1022
2. 5.022 ×1023
3. 6.022 ×1023
4. 5.022 ×1022
1. 4.022 ×1022
2. 5.022 ×1023
3. 6.022 ×1023
4. 5.022 ×1022
Subtopic: Voids, Radius Ratio & Coordination Number |
74%
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A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy 1/3rd of tetrahedral voids. The formula of the compound is-
1. M3 N2
2. M2 N3
3. MN3
4. MN
1. M3 N2
2. M2 N3
3. MN3
4. MN
Subtopic: Voids, Radius Ratio & Coordination Number |
78%
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The lattices has the highest packing efficiency among the following is-
1. Simple cubic
2. Body-centred cubic
3. Hexagonal close-packed lattice
4. None of the above
Subtopic: Density & Packing Fraction |
87%
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An element with molar mass 2.7 × 10-2 kg mol-1 forms a cubic unit cell with edge length 405 pm. If its density is 2.7 × 103 kg m−3, then the nature of the cubic unit cell is-
1. Face-centred cubic
2. Body-centered cubic
3. End-Centred cubic
4. None of the above
1. Face-centred cubic
2. Body-centered cubic
3. End-Centred cubic
4. None of the above
Subtopic: Density & Packing Fraction |
72%
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Heating of a solid favour the -
1. Metal deficiency defect
2. Impurity defects
3. Vacancy defect
4. None of the above
1. Metal deficiency defect
2. Impurity defects
3. Vacancy defect
4. None of the above
Subtopic: Imperfections in Solids & Semiconductors |
61%
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| Statement 1: | ZnS shows Frenkel defect. |
| Statement 2: | AgBr shows Frenkel as well as Schottky defect. |
1. Statement 1 is true , statement 2 is false.
2. Statement 1 is false , statement 2 is true.
3. Both statements are true.
4. Both statements are false.
Subtopic: Imperfections in Solids & Semiconductors |
84%
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When a cation of higher valency is added as an impurity in an ionic solid, then :
1. Vacancies are created .
2. Stoichiometry remains unaffected.
3. Excess of metal ions is created.
4. Both (2) and (3)
1. Vacancies are created .
2. Stoichiometry remains unaffected.
3. Excess of metal ions is created.
4. Both (2) and (3)
Subtopic: Imperfections in Solids & Semiconductors |
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