Q. No.| List-I (Oxoacids of Sulphur) |
List-II (Bonds) |
||
| A. | Peroxodisulphuric acid | I. | Two S-OH, Four S=O, One S-O-S |
| B. | Sulphuric acid | II. | Two S-OH, One S=O |
| C. | Pyrosulphuric acid | III. | Two S-OH, Four S=O, One S-O-O-S |
| D. | Sulphurous acid | IV. | Two S-OH, Two S=O |
| Options: | A | B | C | D |
| 1. | III | IV | II | I |
| 2. | I | III | II | IV |
| 3. | III | IV | I | II |
| 4. | I | III | IV | II |
| Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) |
| Statement II: | The boiling points of these hydrides increase with the increase in molar mass. |
1. Statement I is incorrect but Statement II is correct
2. Both Statement I and Statement II are correct
3. Both Statement I and Statement II are incorrect
4. Statement I is correct but Statement II is incorrect
The correct thermal stability order for \(\mathrm{H}_2 \mathrm{E},\) \(\mathrm{ E}=\mathrm{O}, \mathrm{S}, \mathrm{Se}, \mathrm{Te} \text { and } \mathrm{Po}\) among the following is:
1. \(\mathrm{H}_2 \mathrm{Se}<\mathrm{H}_2 \mathrm{Te}<\mathrm{H}_2 \mathrm{Po}<\mathrm{H}_2 \mathrm{O}<\mathrm{H}_2 \mathrm{~S}\)
2. \(\mathrm{H}_2 \mathrm{~S}<\mathrm{H}_2 \mathrm{O}<\mathrm{H}_2 \mathrm{Se}<\mathrm{H}_2 \mathrm{Te}<\mathrm{H}_2 \mathrm{Po}\)
3. \(\mathrm{H}_2 \mathrm{O}<\mathrm{H}_2 \mathrm{~S}<\mathrm{H}_2 \mathrm{Se}<\mathrm{H}_2 \mathrm{Te}<\mathrm{H}_2 \mathrm{PO}\)
4. \(\mathrm{H}_2 \mathrm{Po}<\mathrm{H}_2 \mathrm{Te}<\mathrm{H}_2 \mathrm{Se}<\mathrm{H}_2 \mathrm{~S}<\mathrm{H}_2 \mathrm{O}\)
Which of the following reactions does not exhibit the oxidising behaviour of H2SO4?
1. Cu + 2H2SO4 → CuSO4 + SO2 + 2H2O
2. 3S + 2H2SO4 → 3SO2 + 2H2O
3. C + 2H2SO4 → CO2 + 2SO2 + 2H2O
4. CaF2 + H2SO4 → CaSO4 + 2HF
Which of the statements given below is incorrect?
1. \(\mathrm{C l_{2} O_{7 }}\)is an anhydride of perchloric acid
2. \(\mathrm{O_{3}}\) molecule is bent
3. ONF is isoelectronic with \(\mathrm{N O_{2}^{-}}\)
4. \(\mathrm{O F_{2}}\) is an oxide of fluorine
The acidity of diprotic acids in aqueous solution increases in the order:
1. H2S < H2Se < H2Te
2. H2Se < H2S < H2Te
3. H2Te < H2S < H2Se
4. H2Se < H2Te < H2S
The given sequence among the following arrangements that is not strictly according to the property indicated against it.
| 1. | H2O < H2S < H2Se < H2Te : \(\small{\text{increasing} \ p K_{a}\ \text{values}}\) |
| 2. | \(\small{\mathrm{N H_{3} < P H_{3} < A s H_{3} < S b H_{3}} : \text{increasing acidic character}}\) |
| 3. | \(\small{\mathrm{C O_{} < S i O_{} < S n O_{} < P b O_{2}} : \text{increasing oxidising power}} \) |
| 4. | \(\small{\mathrm{H F < H C l < H B r < H I} : \text{increasing acidic strength}} \) |
Match List-I (substances) with List-II (processes) employed in the manufacture of the substances and select the correct option.
| List –I (Substances) | List – II (Processes) |
| (a) Sulphuric acid | (i) Haber's Process |
| (b) Steel | (ii) Bessemer's Process |
| (c) Sodium carbonate | (iii) Leblanc Process |
| (d) Ammonia | (iv) Contact Process |
| Options : | (a) | (b) | (c) | (d) |
| 1. | (i) | (ii) | (iii) | (iv) |
| 2. | (iv) | (iii) | (ii) | (i) |
| 3. | (iv) | (ii) | (iii) | (i) |
| 4. | (i) | (iv) | (ii) | (iii) |
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