1. | Se | 2. | Te |
3. | Po | 4. | O |
Statement I: | The boiling point of hydrides of Group 16 elements follow the order \(\text{H}_2 \text{O}>\text{H}_2 \text{Te}>\text{H}_2 \text{Se}>\text{H}_2 \text{S} .\) |
Statement II: | On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point. |
1. | \(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles. |
2. | All five \(\mathrm{P-Cl}\) bonds are identical in length. |
3. | \(\mathrm{PCl_5}\) exhibits sp3d hybridisation. |
4. | \(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds. |
1. | The acidic strength of HX (X=F, Cl, Br and I) follows the order: HF > HCI > HBr >HI |
2. | Fluorine exhibits - 1 oxidation state whereas other halogens exhibit +1, +3, +5 and +7 oxidation states also. |
3. | The enthalpy of dissociation of F2 is smaller than that of Cl2. |
4. | Fluorine is stronger oxidising agent than chlorine. |
1. | \(\mathrm{PEt}_3\) and \(\mathrm{Asph}_3\) as ligands can form \(\mathrm{d} \pi-\mathrm{d} \pi\) bond with transition metals. |
2. | The \(\mathrm{N}-\mathrm{N}\) single bond is as strong as the \(\mathrm{P}-\mathrm{P}\) single bond. |
3. | Nitrogen has unique ability to form \(\mathrm{p \pi-p \pi}\) multiple bonds with nitrogen, carbon and oxygen. |
4. | Nitrogen cannot form \(\mathrm{d} \pi-\mathrm{p} \pi\) bond as other heavier elements of its group. |
List-I (Oxoacids of Sulphur) |
List-II (Bonds) |
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A. | Peroxodisulphuric acid | I. | Two S-OH, Four S=O, One S-O-S |
B. | Sulphuric acid | II. | Two S-OH, One S=O |
C. | Pyrosulphuric acid | III. | Two S-OH, Four S=O, One S-O-O-S |
D. | Sulphurous acid | IV. | Two S-OH, Two S=O |
Options: | A | B | C | D |
1. | III | IV | II | I |
2. | I | III | II | IV |
3. | III | IV | I | II |
4. | I | III | IV | II |
(a) | F–F bond has a low enthalpy of dissociation. |
(b) | Flouride ion (F–) has high hydration enthalpy. |
(c) | Electron gain enthalpy of fluorine is less negative than chlorine. |
(d) | Fluorine has a very small size. |
1. | (a) and (b) only | 2. | (a) and (c) only |
3. | (a) and (d) only | 4. | (b) and (c) only |
1. | \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\) |
2. | \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\) |
3. | \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\) |
4. | \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\) |
Chlorine shows the bleaching action in the presence of moisture due to the formation of
1. HOCl
2. HOClO
3. H2O2
4. O
The correct order for boiling points of the following compounds is:
1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 |
2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 |
3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 |
4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |