Chlorination of methane takes place by:
1. Elimination
2.
3. Free radical
4.
The products formed after ozonolysis of Pent-2-ene are -
1. Ethanal, Methanal
2. Ethanal, Propanal
3. Ethanal, Butanal
4. Ethanal, Ethanal
Among the two isomers given above, the reason behind higher boiling point of one isomer as compared to the order is :
1. Cis - less polar than trans
2. Trans - more polar than cis
3. Cis - more intermolecular forces
4. Trans - more dipole-dipole interactions
Decreasing order of acidic behavior of benzene, n-hexane, and ethyne is -
1. Hexane > Ethyne > Benzene
2. Benzene > Hexane > Ethyne
3. Ethyne > Benzene > Hexane
4. Benzene > Ethyne > Hexene
The reagent used in the above conversion is:
1. Cr2O3
2. Alc. KOH
3. Red hot Fe
4. NaNH2/liq.NH3
Out of the above alkenes, the ones that can give 2-methyl butane on hydrogenation are-
1. | a, b | 2. | b, c |
3. | a, c | 4. | a, b, c |
The correct order of decreasing reactivity of the following compounds:
Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene
with an electrophile (E+) is :
1. | Chlorobenzene > p–Nitrochlorobenzene > 2,4-Dinitrochlorobenzene |
2. | p – Nitro chlorobenzene > 2, 4-Dinitrochlorobenzene > Chlorobenzene |
3. | Chlorobenzene > 2, 4-Dinitrochlorobenzene > p-Nitrochlorobenzene |
4. | 2, 4-Dinitrochlorobenzene > Chlorobenzene > p-Nitrochlorobenzene |
Arrange the following carbanions in order of their decreasing stability:
A. \(\mathrm{H}_3 \mathrm{C}-\mathrm{C} \equiv \mathrm{C}^{-}\)
B. \(\mathrm{H}-\mathrm{C} \equiv \mathrm{C}^{-}\)
C. \(\mathrm{H}_3 \mathrm{C}-\mathrm{\bar{C}H_2}\)
1. A>B>C
2. B>A>C
3. C>B>A
4. C>A>B
The mechanism & intermediate involved in the above reaction are:
1. Aromatic electrophilic substitution & carbocation
2. Aromatic Nucleophilic substitution & carbanion
3. Aromatic free radical substitution & Free radical
4. Carbene based substitution reaction & Carbene
An unsaturated hydrocarbon 'A' reacts with two molecules of H2 and upon reductive ozonolysis A gives butane-1,4-dial, ethanal, and propanone.
The IUPAC name of A is:
1. 2-Methylocta-2,6-diene
2. 2-Methylocta-1,5-diene
3. 3-Methylocta-2,6-diene
4. 2-Methylocta-1,6-diene