The rate constant of a radioactive substance is 4 years-1. The value of half-life will be : 

1. 0.05 years

2. 0.17 years

3. 0.26 years-1

4. 1.6 years

Subtopic:  First Order Reaction Kinetics |
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The rate constant for a first-order reaction is 4.606×10-3 s-1. The time required to reduce 2.0 g of the reactant to 0.2 g will be:

1. 200 s 2. 500 s
3. 1000 s 4. 100 s
Subtopic:  First Order Reaction Kinetics |
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The graph that represents a first-order reaction is:

1.  2.
3. 4.
Subtopic:  First Order Reaction Kinetics |
 85%
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The half-life period for a first-order reaction is 20 minutes. The time required to change the concentration of the reactants from 0.08 M to 0.01 M will be:

1. 20 minutes 2. 60 minutes
3. 40 minutes 4. 50 minutes
Subtopic:  First Order Reaction Kinetics |
 82%
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The half-life of 92U238 against \(\alpha\)-decay is 4.5 × 109 year The time taken in a year for the decay of the 15/16 part of this isotope will be:

1. 9.0×109

2. 1.8×1010

3. 4.5×109

4. 2.7×1010

Subtopic:  First Order Reaction Kinetics |
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The rate constant of a first-order reaction is\(4 \times 10^{-3} \mathrm{sec}^{-1}.\) At a reactant concentration of \(0.02~\mathrm{M},\) the rate of reaction would be:

1. \(8 \times 10^{-5} \mathrm{M} ~\mathrm{sec}^{-1} \) 2. \(4 \times 10^{-3} \mathrm{M} ~\mathrm{sec}^{-1} \)
3. \(2 \times 10^{-1} \mathrm{M}~ \mathrm{sec}^{-1} \) 4. \(4 \times 10^{-1} \mathrm{M}~ \mathrm{sec}^{-1}\)
Subtopic:  First Order Reaction Kinetics |
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The half-life time for the decomposition of a substance dissolved in CCl4 is 2.5 hours at 30 °C. The amount of substance that will be left after 10 hours if the initial weight of the substance is 160 gm is:

1. 20 gm 2. 30 gm
3. 40 gm 4. 10 gm
Subtopic:  First Order Reaction Kinetics |
 75%
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For a reaction of the type 2A + B  2C, the rate of the reaction is given by kA2B. When the volume of the reaction vessel is reduced to 14 th of the original volume, the rate of reaction changes by a factor of -

1. 0.25                                                          

2. 16

3. 64                                                             

4. 4

Subtopic:  Definition, Rate Constant, Rate Law | First Order Reaction Kinetics |
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For the elementary reaction M  N, the rate of disappearance of M increases by a factor of 8 upon doubling the concentration of M. The order of the reaction with respect to M will be:

1. 4

2. 3

3. 2

4. 1

Subtopic:  First Order Reaction Kinetics |
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If ‘a’ is the initial concentration of a substance which reacts according to zero-order kinetics and k is the rate constant, the time for the reaction to go to completion will be:

1. a/k 2. 2/ka
3. k/a 4. Infinite
Subtopic:  Definition, Rate Constant, Rate Law | First Order Reaction Kinetics |
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