The rate constant of a particular reaction has the dimension of frequency. The order of the reaction is: 

1. Zero.                                                     

2. First.

3. Second.                                                 

4. Fractional.

For the reaction, C₂H₅I + OH^- → C₂H₅OH + I^- the rate constant was found to have a value of 5.03 × 10^-2 moI^-1 dm³ s^-1 at 289 K and 6.71 mol^-1 dm³ s^-1 at 333 K. 

The rate constant at 305 K will be: 

$1.$ $1.35$ $mo{l}^{-1}$ $d{m}^3$ $s^{-1}$                  

$2.$ $0.35$ $mo{l}^{-1}$ $d{m}^3$ $s^{-1}$

$3.$ $3.15$ $mo{l}^{-1}$ $d{m}^3$ $s^{-1}$                    

$4.$ $7.14$ $mo{l}^{-1}$ $d{m}^3$ $s^{-1}$

The first order rate constant for a certain reaction increases from\(1.667 \times 10^{-6} \mathrm{~s}^{-1} \text { at } 727^{\circ} \mathrm{C} \text { to } 1.667 \times 10^{-4} \mathrm{~s}^{-1} \text { at } 1571{ }^{\circ} \mathrm{C}.\) The rate constant at \(1150^{\circ} \mathrm{C}\) is: 
(assume activation energy is constant over the given temperature range)

The thermal decomposition of a compound is of first order. If 50 % of a sample of the compound decomposes in 120 minutes, how long will it take for 90 % of the compound to decompose?

1. 399 min                                                        

2. 410 min

3. 250 min                                                        

4. 120 min

The half-life for radioactive decay of ${}^{14}C$ is 5730 y. An archaeological artifact containing wood had only 80 % of the ${}^{14}C$ found in a living tree. The age of the sample will be:

1. 1657.3 y                                                

2. 1845.4 y

3. 1512.4 y                                                

4. 1413.1 y

The following data were obtained during the first-order thermal decomposition of $S{O}_{2}C{l}_2$ at a constant volume.

SO₂Cl₂(g) → SO₂(g) + Cl₂(g)

The rate of the reaction when total pressure is 0.65 atm will be:

1. $7.8$ $\times$ ${10}^{-4}$ $s^{-1}$ $atm.$                                  

2. $0.8$ $\times$ ${10}^{-4}$ $s^{-1}$ $atm.$

3. $2.4$ $\times$ ${10}^{-2}$ $s^{-1}$ $atm.$                                   

4. $6.1$ $\times$ ${10}^{-8}$ $s^{-1}$ $atm.$

At 400 K, the energy of activation of a reaction is decreased by 0.8 kcal in the presence of a catalyst. As a result, the rate will be:

If $∆\mathrm{H}$ of a reaction is 100 kJ mol^-1, then the activation energy for the forward reaction must be

1. Greater than 100 kJ mol^-1

2. Less than 100 kJ mol^-1

3. Equal to 100 kJ mol^-1

4. None of the above.

For the reaction 2N₂O₅(g) → 4NO₂(g) + O₂(g)$,$the concentration of $$ $N{O}_2$ increases by 2.4 × 10^-2 mol L^-1

in 6 seconds. The rate of appearance of $N{O}_2$ and the rate of disappearance of $N_2{O}_5$ , respectively, are:

1. 2 x 10^-3 mol L^-1 sec^-1, 4 x 10^-3 mol L^-1 sec^-1

2. 2 x 10^-3 mol L^-1 sec^-1, 1 x 10^-3 mol L^-1 sec^-1

3. 2 x 10^-3 mol L^-1 sec^-1, 2 x 10^-3 mol L^-1 sec^-1

4. 4 x 10^-3 mol L^-1 sec^-1, 2 x 10^-3 mol L^-1 sec^-1

The decomposition of A into product has value of k as \(4.5 \times 10^3 \mathrm{~s}^{-1} \text { at } 10^{\circ} \mathrm{C}.\) Energy of activation of the reaction is \(60 \mathrm{~kJ}~mol^{-1}.\) The temperature at which value k would become \(1.5\times10^4~s^{-1}\) is :